Municipal wastewater sludge was produced by chemical coagulation of synthetic wastewater (sww) based on Synthene Scarlet P3GL disperse dye and real municipal wastewater (nww), coagulated by commercial coagulants PAX (prepolymerised aluminum coagulant) and PIX (a ferric coagulant based on Fe2(SO4)3). An attempt was made to correlate the sludge’s dewatering capacity (in terms of capillary suction time—CST) with operation parameters for wastewater treatment, size distribution and specific surface area of the sludge particles. It was found that the presence of phosphate ions in the system facilitates the removal efficiency of the above-mentioned dye (L) due to the interaction between the dye molecules and H2PO4− ions. Unlike sww, negatively charged organic substances (sorg) in nww are directly adsorbed on the surface of colloidal particles {Fe(OH)3} and {Al(OH)3} (prtc). It was also discovered that an increase in the dose of a coagulant led to an increase of CST for sww sludge and to a decrease of CST for nww sludge. It has been suggested that flocs composed of spherical {Al(OH)3} units possessed more internal space for water than aggregates consisting of rod-shaped {Fe(OH)3} units and, consequently, it is more difficult to remove water from Al-sww sludge than from Fe-sww. The results obtained showed that smaller particles dominate in sww sludge, while larger particles are prevalent in nww sludge. To explain this distinct difference in the size distribution of particles in sludge obtained with the use of Al3+ and Fe3+, simple models of aggregation and agglomeration-flocculation processes (aaf) of treated wastewater have been proposed. Except for PIX in nww, the analyzed particles of the investigated types of sludge were characterized by similar specific surface area (Sps), regardless of the kind of sludge or the applied coagulant. Slightly larger, negatively-charged sorg bridges, anchored directly on the surface of positive prtc are more effective in closing the structure of nww sludge than small L bridges of the dye molecules anchored on the surface of prtc via H2PO4−. All the discovered aspects could lead to improved performance of wastewater treatment plants (WWTP) by increasing the efficiency of sludge dewatering.

https://www.mdpi.com/2073-4441/11/1/101/pdf/1

Study of Sludge Particles Formed during Coagulation of Synthetic and Municipal Wastewater for Increasing the Sludge Dewatering Efficiency

Electrocoagulation can be effectively used in the elimination of the colloids from the tailings of the mineral industries. Owing to the numerous operational parameters of this physicochemical process, the best engineering technique for the characterization of the process is RSM. In this chapter, a non-transformed quadratic model is firstly formed considering the supernatant turbidity of the electrocoagulation experiments as a function of temperature, pH, and electrical current. Then, the non-normality and the heteroscedasticity of this initial model was indicated. These drawbacks were improved by using the BoxCox transformation with λ of -0.32 and a new model with a perfect normality and homoscedasticity was obtained. The R2 value increased from 81.60% to 99.48% and adjusted R2 increased from 48.48% to 99.22% upon the transformation. According to the confirmed optimization results of the Box-Cox transformed model, the maximum desirability was obtained at pH of 5, temperature of 85°C, and electrical current of 0.25A, and the supernatant turbidity decreased down to 2.25 NTU. Improvement of RSM Prediction and Optimization by Using Box-Cox Transformation: Separation of Colloidal Contaminants From Mineral Processing Effluents via Electrocoagulation

Improvement of RSM Prediction and Optimization by Using Box-Cox Transformation: Separation of Colloidal Contaminants From Mineral Processing Effluents via Electrocoagulation

Smoczynski Michal

Papers

Sizes of particles formed during municipal wastewater treatment