S
Stephen S. Basson
Researcher at University of the Free State
Publications - 100
Citations - 1537
Stephen S. Basson is an academic researcher from University of the Free State. The author has contributed to research in topics: Crystal structure & Reaction mechanism. The author has an hindex of 24, co-authored 99 publications receiving 1487 citations.
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Journal ArticleDOI
Mechanism for the oxidative addition of lodomethane to carbonyl(N-hydroxy-N-nitrosobenzenaminato-O,O′)triarylphosphinerhodium(I) complexes and crystal structure of [Rh(cupf)(CO)(CH3)(1)(PPh3)]
TL;DR: In this article, the reaction proceeds through two competing rate determining steps, one of which is first-order in [CH 3 I], and a reaction mechanism, which includes specific solvent effects, is given.
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The oxidative addition of methyl iodide to β-diketonecarbonyltriphenylphosphinerhodium(I) complexes
TL;DR: In this article, the authors studied the kinetics and mechanism of the reaction [Rh(β-diketone)(CO)(PPh 3 )] + CH 3 I → [RH(βdiketsone)(CH 3 )(I)(CO), where β-dikes = acac, TFDMAA, TFAA and HFAA, with the aid of visible spectrophotometry.
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The crystal structure of 8-hydroxyquinolinatocarbonyltriphenylphosphinerhodium(I)
TL;DR: In this article, the crystal structure of 8-hydroxyquinolinatocarbonyltriphenylphosphine, C 28 H 21 O 2 NPRh, was determined from 2995 unique observed reflections obtained with a computer automated diffractometer.
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Kinetic study of the reaction between trans-dioxotetracyanomolybdate(IV) ions and 1,10-phenanthroline
TL;DR: In this paper, the substitution des coordinats aqua et hydroxo is used to determine the vitesse of pH 8.5 a 12.5. And the substitution of coordinat aqua and hyroxo
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The crystal structure of the 1:2 phenanthroline adduct of sodium oxotricyano‐1,10‐phenanthrolinemolybdate(iv)
TL;DR: The crystal structure of Na[MoO(CN)3(Phen)]· 2Phen was determined from three-dimensional X-ray data as mentioned in this paper, which was solved from 3353 observed reflections which were obtained from a computer automated diffractometer.