The presence of heavy metals in the industrial effluents has recently been a challenging issue for human health. Efficient removal of heavy metal ions from environment is one of the most important issues from biological and environmental point of view, and many studies have been devoted to investigate the environmental behavior of nanoscale zerovalent iron (NZVI) for the removal of toxic heavy metal ions, present both in the surface and underground wastewater. The aim of this review is to show the excellent removal capacity and environmental remediation of NZVI-based materials for various heavy metal ions. A new look on NZVI-based materials (e.g., modified or matrix-supported NZVI materials) and possible interaction mechanism (e.g., adsorption, reduction and oxidation) and the latest environmental application. The effects of various environmental conditions (e.g., pH, temperature, coexisting oxy-anions and cations) and potential problems for the removal of heavy metal ions on NZVI-based materials with the...

Environmental Remediation and Application of Nanoscale Zero-Valent Iron and Its Composites for the Removal of Heavy Metal Ions: A Review

https://www.u-cursos.cl/usuario/7c1c0bd54f14c0722cefc0fa25ea186d/mi_blog/r/Lectura_clase_ingenieria_ambiental.pdf

Arsenic contamination, consequences and remediation techniques: a review

Review on nano zerovalent iron (nZVI): From synthesis to environmental applications

Environmental contamination with arsenic (As) is a global environmental, agricultural and health issue due to the highly toxic and carcinogenic nature of As. Exposure of plants to As, even at very low concentration, can cause many morphological, physiological, and biochemical changes. The recent research on As in the soil-plant system indicates that As toxicity to plants varies with its speciation in plants (e.g., arsenite, As(III); arsenate, As(V)), with the type of plant species, and with other soil factors controlling As accumulation in plants. Various plant species have different mechanisms of As(III) or As(V) uptake, toxicity, and detoxification. This review briefly describes the sources and global extent of As contamination and As speciation in soil. We discuss different mechanisms responsible for As(III) and As(V) uptake, toxicity, and detoxification in plants, at physiological, biochemical, and molecular levels. This review highlights the importance of the As-induced generation of reactive oxygen species (ROS), as well as their damaging impacts on plants at biochemical, genetic, and molecular levels. The role of different enzymatic (superoxide dismutase, catalase, glutathione reductase, and ascorbate peroxidase) and non-enzymatic (salicylic acid, proline, phytochelatins, glutathione, nitric oxide, and phosphorous) substances under As(III/V) stress have been delineated via conceptual models showing As translocation and toxicity pathways in plant species. Significantly, this review addresses the current, albeit partially understood, emerging aspects on (i) As-induced physiological, biochemical, and genotoxic mechanisms and responses in plants and (ii) the roles of different molecules in modulation of As-induced toxicities in plants. We also provide insight on some important research gaps that need to be filled to advance our scientific understanding in this area of research on As in soil-plant systems.

Arsenic uptake, toxicity, detoxification, and speciation in plants : physiological, biochemical, and molecular aspects

Environmental remediation of heavy metal ions by novel-nanomaterials: A review.

Nanofiltration (NF) membranes with positive charge are essential for efficient removal of heavy metals and salts from waste water. In this work surface modified positively charged novel ‘ceramic-supported-polymeric’ (CSP) composite NF membranes were fabricated with the copper ions embedded crosslinked polyethyleneimine polymer matrix over tubular ceramic substrate using facile dipcoating method. EDX, ATR-FTIR, XPS, FESEM, AFM and contact angle analyses were performed to characterize the chemical structures and morphologies of the prepared membranes. The composite NF membrane exhibited satisfactory pure water permeability (PWP) of 8.1 L.m−2.h−1.bar−1 and promising salt (87.19 % and 74.41 % for Mg2+ and Ca2+, respectively) and heavy metal ion rejections (91.73 %, 83.15 % and 75.50 % for Zn2+, Ni2+ and Cd2+, respectively). Activation energy and overall size-exclusion-dehydration phenomena along with steric hindrance and Donnan electrostatic exclusion plays an important role for heavy metals and salts rejection. In addition, the membrane showed excellent antifouling properties (>99 % humic acid removal) with high flux recovery ratio (77.6 %) and low flux decline ratio (33 %) for 5 h operations (3rd cycle) together with outstanding antibiofouling ability towards Brevibacillusagri and Leclerciaadecarboxylata. Furthermore, excellent chemical stability of the membrane suggests its potential application for waste water treatment under critical conditions. 

Fabrication of robust ceramic supported polymeric composite nanofiltration membrane for heavy metal contaminated wastewater treatment

Corrigendum to “Removal of As(V), Cr(VI) and Cu(II) using novel amine functionalized composite nanofiltration membranes fabricated on ceramic tubular substrate” [J. Hazard. Mater. 399 (2020) 122841]

Montmorillonite-supported nZVI: A novel adsorbent for arsenic removal from aqueous solution

The natural occurrence of high dissolved Arsenic (As) in groundwater is quiet common and has been reported from almost entire globe. Nevertheless the scale of problem is most severe in several coun ...

Subhamoy Bhowmick

Papers

Fabrication of robust ceramic supported polymeric composite nanofiltration membrane for heavy metal contaminated wastewater treatment

Corrigendum to “Removal of As(V), Cr(VI) and Cu(II) using novel amine functionalized composite nanofiltration membranes fabricated on ceramic tubular substrate” [J. Hazard. Mater. 399 (2020) 122841]

Montmorillonite-supported nZVI: A novel adsorbent for arsenic removal from aqueous solution

Variation of arsenic in shallow aquifers of the Bengal Basin : Controlling geochemical processes

Voltammetric determination of inorganic arsenic in mildly acidified (pH 4.7) groundwaters from Mexico and India