Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues

Chemical Reviews is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 “Green” Atom Transfer Radical Polymerization: From Process Design to Preparation of Well-Defined Environmentally Friendly Polymeric Materials Nicolay V. Tsarevsky, and Krzysztof Matyjaszewski Chem. Rev., 2007, 107 (6), 2270-2299• DOI: 10.1021/cr050947p • Publication Date (Web): 27 May 2007 Downloaded from http://pubs.acs.org on April 2, 2009

"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.

Structural Aspects of Aromaticity

The special of Chemical Review informs about studies conducted on single-electron transfer and single-electron transfer degenerative chain transfer living radical polymerization. Researchers have demonstrated that living radical polymerization (LRP) can be significantly effective for the synthesis of tailored polymers. The special issue aims at covering the latest progress in two related polymerization methodologies that rely on single-electron transfer (SET), single-electron transfer degenerative chain transfer living radical polymerization (SET-DTLRP), and single-electron transfer living radical polymerization (SET-LRP). It is demonstrated that SET-DTLRP proceeds through SET initiation and competition of SET activation, deactivation, and degenerative transfer (DT). SET-LRP proceeds exclusively through a SET initiation, activation, and deactivation. It is also revealed that the two techniques have arose from investigations into Cu-catalyzed LRP initiated with sulfonyl halides.

Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical Polymerization

Magnetic coupling constants (2J) of hydroxo- and alkoxo-bridged copper binuclear compounds have been evaluated to determine the accuracy of different density functional methods and to study the magnetic behavior of these compounds. Comparison between the calculated and experimental coupling constants for the complete structures of five compounds shows that the most successful computational strategy is the combination of the B3LYP method with the broken-symmetry approach. Calculations for model compounds of both families yield reasonable approximations to the values of magnetic coupling constants calculated for the full molecular structures. Our calculations show a correlation between the magnetic coupling constant and the Cu−O−Cu bridging angle and with the out-of-plane displacement of the hydroxo or alkoxo groups, in agreement with the experimental data. The counterions of the hydroxo-bridged complexes, when hydrogen bonded to the bridging hydroxo group, determine the extent of the out-of-plane displacem...

Toward the Prediction of Magnetic Coupling in Molecular Systems: Hydroxo- and Alkoxo-Bridged Cu(II) Binuclear Complexes

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The Crystal Structure of Al(x)Cu2Mg(12-x)Si7, (h-AlCuMgSi).

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Conformational analysis. the structure and torsional potential of 1,3-butadiene as studied by gas electron diffraction

/pdf/the-crystal-structure-of-tetrapyridine-copper-i-perchlorate-2d2o7di8f4.pdf

The Crystal Structure of Tetrapyridine Copper(I) Perchlorate and Tetrapyridine Silver(I) Perchlorate at 260 K.

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Hydrophilic complexes of the actinides. i. carbonates of trivalent americium and europium

/pdf/the-crystal-structure-of-a-new-oxide-chloride-of-copper-ii-42kcz08yjs.pdf

T. G. Strand

Papers

The Crystal Structure of Al(x)Cu2Mg(12-x)Si7, (h-AlCuMgSi).

Conformational analysis. the structure and torsional potential of 1,3-butadiene as studied by gas electron diffraction

The Crystal Structure of Tetrapyridine Copper(I) Perchlorate and Tetrapyridine Silver(I) Perchlorate at 260 K.

Hydrophilic complexes of the actinides. i. carbonates of trivalent americium and europium

The crystal structure of a new oxide chloride of copper(ii) and selenium(iv): cu5se2o8cl2