Electrochemical lithiation of tin and tin-based intermetallics and composites

Presented herein is a discussion of the forefront in research and development of advanced electrode materials and electrolyte solutions for the next generation of lithium ion batteries. The main challenge of the field today is in meeting the demands necessary to make the electric vehicle fully commercially viable. This requires high energy and power densities with no compromise in safety. Three families of advanced cathode materials (the limiting factor for energy density in the Li battery systems) are discussed in detail: LiMn1.5Ni0.5O4 high voltage spinel compounds, Li2MnO3–LiMO2 high capacity composite layered compounds, and LiMPO4, where M = Fe, Mn. Graphite, Si, LixTOy, and MO (conversion reactions) are discussed as anode materials. The electrolyte is a key component that determines the ability to use high voltage cathodes and low voltage anodes in the same system. Electrode–solution interactions and passivation phenomena on both electrodes in Li-ion batteries also play significant roles in determining stability, cycle life and safety features. This presentation is aimed at providing an overall picture of the road map necessary for the future development of advanced high energy density Li-ion batteries for EV applications.

A review of advanced and practical lithium battery materials

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries

This paper reviews the development of clean vehicles, including pure electric vehicles (EVs), hybrid electric vehicles (HEVs) and fuel cell electric vehicles (FCEVs), and high energy power batteries, such as nickel metal hydride (Ni-MH), lithium-ion (Li-ion) and proton exchange membrane fuel cells (PEMFCs). The mathematical models and thermal behavior of the batteries are described. Details of various thermal management techniques, especially the PCMs battery thermal management system and the materials thermal conductivity, are discussed and compared. It is concluded that the EVs, HEVs and FCEVs are effective to reduce GHG and pollutants emission and save energy. At stressful and abuse conditions, especially at high discharge rates and at high operating or ambient temperatures, traditional battery thermal energy management systems, such as air and liquid, may be not meeting the requirements. Pulsating heat pipe may be more effective but needs to be well designed. In addition, progress in developing new high temperature material is very difficult. PCM for battery thermal management is a better selection than others. Nevertheless, thermal conductivity of the PCMs such as paraffin is low and some methods are adopted to enhance the heat transfer of the PCMs. The performance and thermo-mechanical behaviors of the improved PCMs in the battery thermal management system need to be investigated experimentally. And the possibility of the heat collection and recycling needs to be discussed in terms of energy saving and efficient.

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A review of power battery thermal energy management

Presents here a complete dynamic model of a lithium ion battery that is suitable for virtual-prototyping of portable battery-powered systems. The model accounts for nonlinear equilibrium potentials, rate- and temperature-dependencies, thermal effects and response to transient power demand. The model is based on publicly available data such as the manufacturers' data sheets. The Sony US18650 is used as an example. The model output agrees both with manufacturer's data and with experimental results. The model can be easily modified to fit data from different batteries and can be extended for wide dynamic ranges of different temperatures and current rates.

Dynamic lithium-ion battery model for system simulation

A methanol fuel cell wherein a positive electrode (2) and a negative electrode (1) are disposed in contact with a solid film (3) which exhibits a hydrogen ion- and/ or hydronium ion-conductivity. The methanol permeability coefficient of the solid film (3) of the methanol fuel cell is at most 1 x 10-6 mol/mol/l).min.cm2.

Methanol fuel cell

X-ray photoelectron spectroscopy analyses of lithium intercalation and alloying reactions on graphite electrodes

Provided is a solid polymer electrolyte type fuel cell which is improved in cell output characteristics by preventing the flooding phenomenon at the interface between the oxygen electrode and the electrolyte membrane, accelerating the gas diffusion and effective utilization of the active surface of the catalyst. This solid polymer electrolyte type fuel cell comprises solid polymer electrolyte membrane 1 and gas diffusion electrodes 2 and 3 provided on both sides of the membrane, said gas diffusion electrodes comprising catalyst layers 6 and 8 and gas diffusion layers 7 and 9 being provided on the outer side of the respective catalyst layers and a hydrogen-containing gas and an oxygen-containing gas being fed to the respective electrodes. In this cell, the water-repellency of the hydrogen electrode 2 is higher than that of the oxygen electrode 3 and furthermore, a gradient of water-repellency is provided in the catalyst layer of each electrode so that the water-repellency in the portion facing to the electrolyte membrane is higher than that in the portion facing to the gas diffusion layer in each catalyst layer. The output density of the cell according to the present invention is as high as 2-3 times that of conventional cells.

Solid polymer electrolyte type fuel cell

In a fuel cell having a fuel electrode, an oxidant electrode, and an electrolyte which is located between both the electrodes, a methanol concentration control device is disposed, at a pipe which supplies the fuel to the fuel cell for controlling the amount of the methanol in the pipe by detecting the open-circuit voltage of the unit cell or the open-circuit potential of the oxidant cell at the methanol concentration control device.

Tatsuo Horiba

Papers

Methanol fuel cell

X-ray photoelectron spectroscopy analyses of lithium intercalation and alloying reactions on graphite electrodes

Solid polymer electrolyte type fuel cell

Fuel cell comprising a device for detecting the concentration of methanol

Development of a high power lithium secondary battery for hybrid electric vehicles