Since the discovery of mechanically exfoliated graphene in 2004, research on ultrathin two-dimensional (2D) nanomaterials has grown exponentially in the fields of condensed matter physics, material science, chemistry, and nanotechnology. Highlighting their compelling physical, chemical, electronic, and optical properties, as well as their various potential applications, in this Review, we summarize the state-of-art progress on the ultrathin 2D nanomaterials with a particular emphasis on their recent advances. First, we introduce the unique advances on ultrathin 2D nanomaterials, followed by the description of their composition and crystal structures. The assortments of their synthetic methods are then summarized, including insights on their advantages and limitations, alongside some recommendations on suitable characterization techniques. We also discuss in detail the utilization of these ultrathin 2D nanomaterials for wide ranges of potential applications among the electronics/optoelectronics, electrocat...

Recent Advances in Ultrathin Two-Dimensional Nanomaterials

Graphene and other two-dimensional materials, such as transition metal dichalcogenides, have rapidly established themselves as intriguing building blocks for optoelectronic applications, with a strong focus on various photodetection platforms The versatility of these material systems enables their application in areas including ultrafast and ultrasensitive detection of light in the ultraviolet, visible, infrared and terahertz frequency ranges These detectors can be integrated with other photonic components based on the same material, as well as with silicon photonic and electronic technologies Here, we provide an overview and evaluation of state-of-the-art photodetectors based on graphene, other two-dimensional materials, and hybrid systems based on the combination of different two-dimensional crystals or of two-dimensional crystals and other (nano)materials, such as plasmonic nanoparticles, semiconductors, quantum dots, or their integration with (silicon) waveguides

http://www-g.eng.cam.ac.uk/nms/publications/pdf/nnano.2014.215.pdf

Photodetectors based on graphene, other two-dimensional materials and hybrid systems

Graphene and related two-dimensional crystals and hybrid systems showcase several key properties that can address emerging energy needs, in particular for the ever growing market of portable and wearable energy conversion and storage devices. Graphene's flexibility, large surface area, and chemical stability, combined with its excellent electrical and thermal conductivity, make it promising as a catalyst in fuel and dye-sensitized solar cells. Chemically functionalized graphene can also improve storage and diffusion of ionic species and electric charge in batteries and supercapacitors. Two-dimensional crystals provide optoelectronic and photocatalytic properties complementing those of graphene, enabling the realization of ultrathin-film photovoltaic devices or systems for hydrogen production. Here, we review the use of graphene and related materials for energy conversion and storage, outlining the roadmap for future applications.

Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage

Physical Review B

Annual review of condensed matter physics

We investigate the dc current-voltage characteristics of d-wave Josephson junctions, where the barrier at the interface may have arbitrary strength. Dividing the current into n-particle currents $I_n$ (n integer), we can explicitly show which physical processes are responsible for the subharmonic gap structure (SGS). For orientations where midgap states (MGS) exist, the resonances in the n-particle processes are drastically changed, giving rise to a strongly modified SGS. Introducing broadening in a phenomenological way, we show that MGS may produce a current peak near zero bias and we explain which physical processes are contributing to this peak. The agreement of our theory with recent experiments is discussed.

https://arxiv.org/pdf/cond-mat/9908261.pdf

Current-Voltage Relations in d-wave Josephson Junctions: Effects of Midgap Interface States

In an unconventional superconductor, the interplay of scattering off impurities and Andreev processes may lead to different scattering times for electronlike and holelike quasiparticles. Such electron-hole asymmetry appears when the impurity scattering phase shift is intermediate between the Born and unitary limits and leads to an expectation for large thermoelectric effects. Here, we examine the thermoelectric response of a $d$-wave superconductor connected to normal-metal reservoirs under a temperature bias using a fully self-consistent quasiclassical theory. The thermoelectrically induced quasiparticle current is cancelled by superflow in an open circuit setup, but at the cost of a charge imbalance induced at the contacts and extending across the structure. We investigate the resulting thermopower and thermophase and their dependencies on scattering phase shift, mean free path, and interface transparency. For crystal-axis orientations such that surface-bound zero-energy Andreev states are formed, the thermoelectric effect is reduced as a result of locally reduced electron-hole asymmetry. For a semiballistic superconductor with good contacts, we find thermopowers of order several ${\mu}V/K$, suggesting a thermovoltage measurement as a promising path to investigate thermoelectricity in unconventional superconductors. 

Thermopower and thermophase in a 
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-wave superconductor

The formation of quasiparticle zero-energy bound states at surfaces and interfaces of high-Tc superconductors is a direct consequence of the d-wave symmetry of the order parameter. In many cases it is possible to understand the novel physics appearing at surfaces/interfaces of d-wave superconductors by a simple consideration of the specific properties of the zero-energy states. Here we discuss how the large zero-energy density of states makes breaking of time-reversal symmetry energetically favorable, both at surfaces and at Josephson junctions. 2001 Elsevier Science B.V. All rights reserved.

Properties of zero-energy surface states in d-wave superconducting junctions

We report results for the electronic thermal conductivity in d‐wave superconductors at low temperatures, including effects of anisotropic impurity scattering.

/pdf/low-temperature-thermal-conductivity-of-superconductors-with-3f4f3xlah2.pdf

Low‐Temperature Thermal Conductivity of Superconductors With Gap Nodes

Non-equilibrium phenomena in superconductors have attracted much attention since the first experiments on charge imbalance in the early 1970's. Nowadays a new promising line of research lies at an intersection between superconductivity and spintronics. Here we develop a quasiclassical theory of a single junction between a normal metal and a superconductor with a spin-active interface at finite bias voltages. Due to spin-mixing and spin-filtering effects of the interface a non-equilibrium magnetization (or spin imbalance) is induced at the superconducting side of the junction, which relaxes to zero in the bulk. A peculiar feature of the system is the presence of interface-induced Andreev bound states, which influence the magnitude and the decay length of spin imbalance. Recent experiments on spin and charge density separation in superconducting wires required external magnetic field for observing a spin signal via non-local measurements. Here, we propose an alternative way to observe spin imbalance without applying magnetic field.

https://publications.lib.chalmers.se/records/fulltext/208690/local_208690.pdf

Tomas Löfwander

Papers

Current-Voltage Relations in d-wave Josephson Junctions: Effects of Midgap Interface States

Thermopower and thermophase in a <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mi>d</mml:mi></mml:math> -wave superconductor

Properties of zero-energy surface states in d-wave superconducting junctions

Low‐Temperature Thermal Conductivity of Superconductors With Gap Nodes

Quasiclassical Theory of Spin Imbalance in a Normal Metal-Superconductor Heterostructure with a Spin-Active Interface