Tomasz Kliś

TL;DR: The synthesis and physicochemical properties of benzosiloxaboroles, the silicon analogues of an important class of heterocyclic compounds, are presented in this paper, where they were prepared by halogen-lithium exchange reactions of (2-bromophenyl)boronates with n-BuLi.

TL;DR: In this paper, a series of aryl benzyl ethers containing halogen substituents was investigated and the resultant mono- and diorganolithium intermediates were converted into corresponding aldehydes or diboronic acids in good yields.

TL;DR: In this article, the development of a visible light-mediated atom transfer radical addition (ATRA) of perfluoroalkyl iodides to ethynyl-, vinyl- and allyl-MIDA boronates using the reductive and oxidative quenching of [Ru(bpy)3]Cl2 is described.

TL;DR: Cyclic voltammetry studies revealed that electrochemical behavior of cationic versus betaine structures is different in terms of redox potential values as well as stability, and a different scheme for molecular excitation processes in B(OH)2 versus BF3-substituted compounds as charge transfer to acridinium core is observed from N-aryl or B-aryl moiety, respectively.

TL;DR: In this paper, molecular and crystal structures of monobenzoyl tartaric acid (1) and its anhydride (2) were determined and analyzed, and it was shown that the conformation of 1 results from strong intermolecular interactions.