T
Tomohito Morosaki
Researcher at College of Industrial Technology
Publications - 6
Citations - 74
Tomohito Morosaki is an academic researcher from College of Industrial Technology. The author has contributed to research in topics: Lone pair & Electron donor. The author has an hindex of 4, co-authored 6 publications receiving 64 citations.
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Journal ArticleDOI
Syntheses, structures, and reactivities of two chalcogen-stabilized carbones.
TL;DR: Analysis of a doubly protonated dication and trication complex revealed that the central carbon atom of 2 behaves as a four-electron donor, which means the carbone 2 is the first carbone containing selenium as the coordinated atom.
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Synthesis, Structure, and Reactivities of Iminosulfane‐ and Phosphane‐Stabilized Carbones Exhibiting Four‐Electron Donor Ability
TL;DR: These results are the first experimental evidence of phosphorus- and sulfur-stabilized carbones behaving as four-electron donors and can be used as carbone transfer agents for moisture-sensitive carbone species.
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Synthesis, Electronic Structure, and Reactivities of Two-Sulfur-Stabilized Carbones Exhibiting Four-Electron Donor Ability.
TL;DR: The syntheses and application of AgI carbone complexes as carbone transfer agents are reported and the first experimental evidence for two-sulfur-stabilized carbones behaving as four-electron donors is provided.
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Syntheses and Structural Characterization of Mono-, Di-, and Tetranuclear Silver Carbone Complexes
TL;DR: In this article, a bis(chalcogenane) carbon(0) (BChC)-bearing iminosulfane ligand was successfully synthesized and isolated using a tetranuclear silver complex.
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Synthesis of phosphorus- and sulfur-stabilized carbone (Me)Ph2P→C←SPh2(= NMe)
TL;DR: Iminosulfane(phosphane) carbon(0) (iSPC) is generated by the deprotonation of corresponding cationic salt 1·H, which is obtained from the reaction of iminosulfonium methy...