T
Toshiyasu Sakakura
Researcher at Ibaraki University
Publications - 7
Citations - 693
Toshiyasu Sakakura is an academic researcher from Ibaraki University. The author has contributed to research in topics: Catalysis & Dimethyl carbonate. The author has an hindex of 6, co-authored 7 publications receiving 668 citations.
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Selective Conversion of Carbon Dioxide to Dimethyl Carbonate by Molecular Catalysis.
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Reaction of Dialkyltin Methoxide with Carbon Dioxide Relevant to the Mechanism of Catalytic Carbonate Synthesis
TL;DR: In this article, the authors have recently enhanced the catalytic efficiency of R{sub 2]Sn(OMe){sub 2} using dehydrated derivatives of methanol (eg, ortho esters and acetals) as a starting material under supercritical CO sub 2 conditions.
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Synthesis of dimethyl carbonate from carbon dioxide: catalysis and mechanism
TL;DR: In this paper, a possible catalytic cycle involving transformation of CO2 to dimethyl carbonate is postulated based on mechanistic studies at a molecular level, and the catalytic efficiency is remarkably improved using an acetal as the starting material in methanol.
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Metal-Catalyzed Dimethyl Carbonate Synthesis from Carbon Dioxide and Acetals
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Total synthesis of a macrocyclic pyrrolizidine alkaloid, (.+-.)-integerrimine, utilizing an activable protecting group
TL;DR: Synthese a partir de retronecine et d'acide d'integerrinecique en utilisant le groupe methylthiomethyl comme groupe protecteur activable de la fonction acide as discussed by the authors.