[1] We use the Total Ozone Mapping Spectrometer (TOMS) sensor on the Nimbus 7 satellite to map the global distribution of major atmospheric dust sources with the goal of identifying common environmental characteristics The largest and most persistent sources are located in the Northern Hemisphere, mainly in a broad “dust belt” that extends from the west coast of North Africa, over the Middle East, Central and South Asia, to China There is remarkably little large-scale dust activity outside this region In particular, the Southern Hemisphere is devoid of major dust activity Dust sources, regardless of size or strength, can usually be associated with topographical lows located in arid regions with annual rainfall under 200–250 mm Although the source regions themselves are arid or hyperarid, the action of water is evident from the presence of ephemeral streams, rivers, lakes, and playas Most major sources have been intermittently flooded through the Quaternary as evidenced by deep alluvial deposits Many sources are associated with areas where human impacts are well documented, eg, the Caspian and Aral Seas, Tigris-Euphrates River Basin, southwestern North America, and the loess lands in China Nonetheless, the largest and most active sources are located in truly remote areas where there is little or no human activity Thus, on a global scale, dust mobilization appears to be dominated by natural sources Dust activity is extremely sensitive to many environmental parameters The identification of major sources will enable us to focus on critical regions and to characterize emission rates in response to environmental conditions With such knowledge we will be better able to improve global dust models and to assess the effects of climate change on emissions in the future It will also facilitate the interpretation of the paleoclimate record based on dust contained in ocean sediments and ice cores

https://agupubs.onlinelibrary.wiley.com/doi/epdf/10.1029/2000RG000095

Environmental characterization of global sources of atmospheric soil dust identified with the nimbus 7 total ozone mapping spectrometer (toms) absorbing aerosol product

The environmental conditions of Earth, including the climate, are determined by physical, chemical, biological, and human interactions that transform and transport materials and energy. This is the "Earth system": a highly complex entity characterized by multiple nonlinear responses and thresholds, with linkages between disparate components. One important part of this system is the iron cycle, in which iron-containing soil dust is transported from land through the atmosphere to the oceans, affecting ocean biogeochemistry and hence having feedback effects on climate and dust production. Here we review the key components of this cycle, identifying critical uncertainties and priorities for future research.

/pdf/global-iron-connections-between-desert-dust-ocean-43atskudjz.pdf

Global Iron Connections Between Desert Dust, Ocean Biogeochemistry, and Climate

The global distribution of dust aerosol is simulated with the Georgia Tech/Goddard Global Ozone Chemistry Aerosol Radiation and Transport (GOCART) model. In this model all topographic lows with bare ground surface are assumed to have accumulated sediments which are potential dust sources. The uplifting of dust particles is expressed as a function of surface wind speed and wetness. The GOCART model is driven by the assimilated meteorological fields from the Goddard Earth Observing System Data Assimilation System (GEOS DAS) which facilitates direct comparison with observations. The model includes seven size classes of mineral dust ranging from 0.1–6 μm radius. The total annual emission is estimated to be between 1604 and 1960 Tg yr−1 in a 5-year simulation. The model has been evaluated by comparing simulation results with ground-based measurements and satellite data. The evaluation has been performed by comparing surface concentrations, vertical distributions, deposition rates, optical thickness, and size distributions. The comparisons show that the model results generally agree with the observations without the necessity of invoking any contribution from anthropogenic disturbances to soils. However, the model overpredicts the transport of dust from the Asian sources to the North Pacific. This discrepancy is attributed to an overestimate of small particle emission from the Asian sources.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2000JD000053

Sources and distributions of dust aerosols simulated with the GOCART model

We present estimates of total nitrogen and total phosphorus fluxes in rivers to the North Atlantic Ocean from 14 regions in North America, South America, Europe, and Africa which collectively comprise the drainage basins to the North Atlantic. The Amazon basin dominates the overall phosphorus flux and has the highest phosphorus flux per area. The total nitrogen flux from the Amazon is also large, contributing 3.3 Tg yr-1 out of a total for the entire North Atlantic region of 13.1 Tg yr-1. On a per area basis, however, the largest nitrogen fluxes are found in the highly disturbed watersheds around the North Sea, in northwestern Europe, and in the northeastern U.S., all of which have riverine nitrogen fluxes greater than 1,000 kg N km-2 yr-1.

Regional nitrogen budgets and riverine N & P fluxes for the drainages to the North Atlantic Ocean: Natural and human influences

The terrestrial biosphere plays an important role in the global carbon cycle. In the 1994 Intergovernmental Panel Assessment on Climate Change (IPCC), an effort was made to improve the quantification of terrestrial exchanges and potential feedbacks from climate, changing CO2, and other factors; this paper presents the key results from that assessment, together with expanded discussion. The carbon cycle is the fluxes of carbon among four main reservoirs: fossil carbon, the atmosphere, the oceans, and the terrestrial biosphere. Emissions of fossil carbon during the 1980s averaged 5.5 Gt y−1. During the same period, the atmosphere gained 3.2 Gt C y−1 and the oceans are believed to have absorbed 2.0 Gt C y−1. The regrowing forests of the Northern Hemisphere may have absorbed 0.5 Gt C y−1 during this period. Meanwhile, tropical deforestation is thought to have released an average 1.6 Gt C y−1 over the 1980s. While the fluxes among the four pools should balance, the average 198Ds values lead to a ‘missing sink’ of 1.4 Gt C y−1 Several processes, including forest regrowth, CO2 fertilization of plant growth (c. 1.0 Gt C y−1), N deposition (c. 0.6 Gt C y−1), and their interactions, may account for the budget imbalance. However, it remains difficult to quantify the influences of these separate but interactive processes. Uncertainties in the individual numbers are large, and are themselves poorly quantified. This paper presents detail beyond the IPCC assessment on procedures used to approximate the flux uncertainties.

Lack of knowledge about positive and negative feedbacks from the biosphere is a major limiting factor to credible simulations of future atmospheric CO2 concentrations. Analyses of the atmospheric gradients of CO2 and 13 CO2 concentrations provide increasingly strong evidence for terrestrial sinks, potentially distributed between Northern Hemisphere and tropical regions, but conclusive detection in direct biomass and soil measurements remains elusive.

Current regional-to-global terrestrial ecosystem models with coupled carbon and nitrogen cycles represent the effects of CO2 fertilization differently, but all suggest longterm responses to CO2 that are substantially smaller than potential leaf- or laboratory whole plant-level responses. Analyses of emissions and biogeochemical fluxes consistent with eventual stabilization of atmospheric CO2 concentrations are sensitive to the way in which biospheric feedbacks are modeled by c. 15%. Decisions about land use can have effects of 100s of Gt C over the next few centuries, with similarly significant effects on the atmosphere.

Critical areas for future research are continued measurements and analyses of atmospheric data (CO2 and 13CO2) to serve as large-scale constraints, process studies of the scaling from the photosynthetic response to CO2 to whole-ecosystem carbon storage, and rigorous quantification of the effects of changing land use on carbon storage.

Terrestrial ecosystems and the carbon cycle

Over the past decade it has become apparent that the atmosphere is a significant pathway for the transport of many natural and pollutant materials from the continents to the ocean. The atmospheric input of many of these species can have an impact (either positive or negative) on biological processes in the sea and on marine chemical cycling. For example, there is now evidence that the atmosphere may be an important transport path for such essential nutrients as iron and nitrogen in some regions. In this report we assess current data in this area, develop global scale estimates of the atmospheric fluxes of trace elements, mineral aerosol, nitrogen species, and synthetic organic compounds to the ocean; and compare the atmospheric input rates of these substances to their input via rivers. Trace elements considered were Pb, Cd, Zn, Cu, Ni, As, Hg, Sn, Al, Fe, Si, and P. Oxidized and reduced forms of nitrogen were considered, including nitrate and ammonium ions and the gaseous species NO, NO2, HNO3, and NH3. Synthetic organic compounds considered included polychlorinated biphenyls (PCBs), hexachlorocyclohexanes (HCHs), DDTs, chlordane, dieldrin, and hexachlorobenzenes (HCBs). Making this assessment was difficult because there are very few actual measurements of deposition rates of these substances to the ocean. However, there are considerably more data on the atmospheric concentrations of these species in aerosol and gaseous form. Mean concentration data for 10° × 10° ocean areas were determined from the available concentration data or from extrapolation of these data into other regions. These concentration distributions were then combined with appropriate exchange coefficients and precipitation fields to obtain the global wet and dry deposition fluxes. Careful consideration was given to atmospheric transport processes as well as to removal mechanisms and the physical and physicochemical properties of aerosols and gases. Only annual values were calculated. On a global scale atmospheric inputs are generally equal to or greater than riverine inputs, and for most species atmospheric input to the ocean is significantly greater in the northern hemisphere than in the southern hemisphere. For dissolved trace metals in seawater, global atmospheric input dominates riverine input for Pb, Cd, and Zn, and the two transport paths are roughly equal for Cu, Ni, As, and Fe. Fluxes and basin-wide deposition of trace metals are generally a factor of 5-10 higher in the North Atlantic and North Pacific regions than in the South Atlantic and South Pacific. Global input of oxidized and reduced nitrogen species are roughly equal to each other, although the major fraction of oxidized nitrogen enters the ocean in the northern hemisphere, primarily as a result of pollution sources. Reduced nitrogen species are much more uniformly distributed, suggesting that the ocean itself may be a significant source. The global atmospheric input of such synthetic organic species as HCH,PCBs, DDT, and HCB completely dominates their input via rivers.

The atmospheric input of trace species to the world ocean

The concentrations of trace elements in aerosol particles from the atmosphere over the North Atlantic Ocean were determined as part of a program designed to characterize the chemical climatology of the region. For these studies, which were part of the Atmosphere- Ocean Chemistry Experiment (AEROCE), 2 years of samples were collected at Tudor Hill, Bermuda (BTT), and at Ragged Point, Barbados (BAT); and 1 year of samples was collected at Mace Head, Ireland (MHT) and at the Izafia Observatory, Tenerife, Canary Islands (IZT). One major component of the aerosol was atmospheric dust, and the ranking for the median mineral dust concentrations as represented by aluminum was BAT > IZT > BTT > MHT. The A1 concentrations at BAT, IZT, and BTT ranged over 4 orders of magnitude, i.e., from 0.001 to 10 gg m -3. At MHT the maximum dust concentrations were about a factor of 10 lower than at the other sites, but the lower end of the range in dust concentrations was similar at all sites. The mineral dust concentrations generally were highest in summer, and the flux of atmospheric dust was dominated by sources in North Africa. The elements showing clear enrichments over the concentrations expected from sea salt or crustal sources were I, Sb, Se, V, and Zn. At Izafia, which is in the free troposphere (elevation -2360 m), the concentrations of Se and I were much lower than at the boundary layer sites; this difference between sites most likely results from the marine emissions of these elements. The impact of pollution sources on trace element concentrations was evident at all sites but varied with season and location. The concentrations of elements originating from pollution sources generally were low at Barbados. Analyses of trace element ratios indicate that there are large-scale differences in the pollution emissions from North America versus those from Europe and Africa. Emissions from pyrometallurgical industries, steel and iron manufacturing, and possibly biomass burning are more evident in the atmospheric samples influenced by transport from Europe and Africa.

Trace elements in the atmosphere over the North Atlantic

Synthetic records of percent CaCO 3 , carbonate mass accumulation, and noncarbonate (terrigenous) mass accumulation are developed for late Neogene portions of Ceara Rise Sites 925-929. Shipboard measurements of natural gamma emissions and magnetic susceptibility, collected at 3- to 10-cm intervals at each site, are combined with equally high resolution measurements of digital color reflectance to estimate lithologic variations over the whole sequence. Where magnetic susceptibility and natural gamma were measured in adjacent holes, the between-hole meters composite depth (mcd) scale was refined so that all data from a given site could be combined. A linear regression model is developed that predicts percent CaCO 3 from high-resolution measurements of stacked natural gamma emissions, stacked magnetic susceptibility, and digital color reflectance. Over 1300 measurements of percent CaCO 3 were made to develop a robust regression equation for each site. An orbitally calibrated chronology for Sites 925-929 relates all data to a common temporal framework. Carbonate and noncarbonate (terrigenous) mass accumulation rates are estimated from 5 to 14 Ma at Sites 925-929. These data are in turn used to evaluate variations in the lysocline from the Miocene to Holocene as a function of depth and time. Over the depth transect, CaCO 3 fluxes during the Miocene undergo significant changes, most likely owing to development and intensification of North Atlantic Deep Water during the late Miocene. Terrigenous fluxes show a long-term trend of increasing accumulation in response to Andean uplift and late Miocene development of the Amazon drainage into the Atlantic Ocean.

Miocene evolution of carbonate sedimentation at the Ceara Rise : A multivariate data/proxy approach

Daily aerosol samples collected at Bermuda and Barbados as part of the Atmosphere/Ocean Chemistry Experiment (AEROCE) were analyzed to evaluate the sources for selenium (Se). Isentropic trajectories were used to further evaluate the sources suggested by the chemical information. At Bermuda, the major source for Se was anthropogenic emissions from North America. Daily Se concentrations were highly correlated with antimony (Sb) which originated from a pollution source. However, approximately 6% of the Sb was associated with mineral dust from northern Africa that reached Bermuda during the summer months. The Bermuda aerosol data showed a weak correlation between Se and methane sulfonate (MSA), but the intercept of the Se versus Sb regression indicated that a marine biogenic source of Se accounted for ∼45% of the mean concentration at Bermuda. At Barbados the variability of Se concentrations could not be explained solely by pollution sources. Correlations between Se and Sb, nitrate (NO3−), non-sea-salt sulfate (nssSO4=), and MSA were significant. The correlations of Se with Sb, NO3−, and nssSO4= suggested continental sources. The correlation with MSA indicated there was a significant marine biogenic source. Our results indicated that a marine biogenic source of Se accounted for 60–80% of the Se at Barbados. Analyses of seasonal relationships indicated that the marine biogenic source was most important during the summer.

Aerosol Selenium at Bermuda and Barbados

Atmospheric chemistry programs often make use of retrospective back trajectories to determine the source regions of substances sampled at a particular site. Isentropic trajectories, which depict motion on hypothetical surfaces of constant potential temperature, have been used as part of the Atmosphere/Ocean Chemistry Experiment to understand the sources of aerosols and gases sampled over the North Atlantic Ocean. However, isentropic trajectories typically do not adequately describe the transport of mineral aerosol, for example, from the Sahara Desert to Barbados. Boundary layer trajectories indicated that northern Africa was the source region for 12% of the samples with significant aluminum (Al) concentrations (> 1.0 µg m−3). Upper-level isentropic trajectories (310 and 315 K) indicated transport from northern Africa for approximately half of the samples with Al concentrations greater than 1.0 µg m−3. However, at the location of the sampling site, the upper-level trajectories were well above the ...

W. G. Ellis

Papers

The atmospheric input of trace species to the world ocean

Trace elements in the atmosphere over the North Atlantic

Miocene evolution of carbonate sedimentation at the Ceara Rise : A multivariate data/proxy approach

Aerosol Selenium at Bermuda and Barbados

Trajectories for Saharan Dust Transported to Barbados Using Stokes's Law to Describe Gravitational Settling