https://escholarship.org/content/qt974348kc/qt974348kc.pdf?t=pghxgl

Nuclear Data Sheets for A=138

High-spin states of $^{138}\mathrm{Pm}$ have been populated using the $^{124}\mathrm{Te}(^{19}\mathrm{F},\phantom{\rule{0.28em}{0ex}}5\mathrm{n})^{138}\mathrm{Pm}$ reaction at a beam energy of 105 MeV. A new positive-parity side band with the same $\ensuremath{\pi}{h}_{11/2}\ensuremath{\bigotimes}\ensuremath{\nu}{h}_{11/2}$ configuration as that of the yrast band is observed in $^{138}\mathrm{Pm}$. The properties of the two positive-parity bands show general agreement with the fingerprints of chiral rotation and thus these two bands are suggested to be candidates for near degenerate chiral doublet bands. Besides, odd-even spin staggering of the $\ensuremath{\pi}{h}_{11/2}\ensuremath{\bigotimes}\ensuremath{\nu}{h}_{11/2}$ bands is studied systematically in odd-odd Cs, La, Pr, and Pm isotopes. As a result of this study we suggest that the spin value of lowest observed state of the yrast band be reassigned as 9 in $^{138}\mathrm{Pm}$. This new spin assignment is also supported by the argument of alignment additivity.

Candidate chiral doublet bands in Pm 138

A large wealth of data and a variety of models led to significant progress in understanding the spectra of deformed nuclei. However, a robust theoretical approach, which is less reliant on adjustable parameters is still elusive. Due to the scarcity of data, this drawback gets more pronounced while studying the exotic nuclei. With the motive to overcome this difficulty, we have developed the nonadiabatic quasiparticle approach for the description of rotational states in triaxial deformed odd–odd nuclei. The rotation-particle coupling is carried out utilizing an appropriate basis transformation such that the matrix elements of the odd–odd system can be written in terms of the rotor energies. This provides the advantage of studying the role of core more efficiently as compared to the conventional particle rotor model. The residual interaction between the valence proton and neutron is incorporated in two reliable ways, namely, the constant potential form and the zero-range interaction.

Nonadiabatic quasiparticle description of rotation-particle coupling in triaxial odd–odd nuclei

Vibrational and computational data for homoleptic main-group element carbonyl complexes

The neutral (NN)-B-B-B-(N2) complex has been trapped in low-temperature dinitrogen matrix and identified by isotopic substitution and theoretical frequency calculations. The linear B-B-B skeleton is stabilized by two inequivalent N2, namely, one end-on and other side-on N2. The structure of linear B-B-B skeleton illustrates much difference from previously reported triangle configuration of B3 clusters. Frontier orbital analysis demonstrates that the σ orbital of end-on NN and the π-bonding orbital of side-on N2 acts as the donor orbital. π bonding character across B-B-B skeleton donates to the antibonding π* orbital of end-on NN and out of phase the B-B-B features π back-donation to antibonding π* orbital of side-on N2. The combination of strong σ-donating capacity coupled with a greater ability for accepting π-back-donation of the N2 ligand leads to the formation of (NN)-B-B-B-(N2) complex with linear B-B-B skeleton. In addition, complexes of (NN)B(NN), (NN)BB(NN), and (NN)B4(NN) have been identified in our experiments.

Complex with Linear B-B-B Skeleton Trapped in Dinitrogen Matrix: Matrix Infrared Spectra and Quantum Chemical Calculations.

The high-spin states in the odd-odd 138Pm nucleus have been reinvestigated via the 124Te(19F, 5n) reaction at the beam energy of 103 MeV. Most of the known transitions and levels are confirmed. A number of bands are revised and one new band has been established. For the yrast πh
 11/2⊗νh
 11/2 band based on 8+ state, no evidence supporting the occurence of signature inversion is found. The experimental and theoretical B(M1)/B(E2) ratios have been calculated for band (2), which support the πg
 7/2[413]5/2+ ⊗ νh
 11/2[514]9/2− Nilsson configuration assignment. Four bands with ΔI = 2 transitions are tentatively assigned as doubly decoupled bands. The other three bands are proposed as oblate-triaxial bands. The possible configuration assignments for these bands are also discussed under the calculations of total Routhian surface and particle-rotor model.

Reinvestigation of the collective band structures in odd-odd 138Pm nucleus

A neutral boron carbonyl complex B4 (CO)3 is generated in the gas phase and is characterized by infrared plus vacuum ultraviolet (IR+VUV) two-color ionization spectroscopy and quantum chemical calculations. The complex is identified to have a planar C2v structure with three CO ligands terminally coordinated to a rhombus B4 core. It has a closed-shell singlet ground state that correlates to an excited state of B4 . Bonding analyses on B4 (CO)3 as well as the previously reported B4 and B4 (CO)2 indicate that the electronic structure of rhombus tetraboron cluster changes from a close-shell singlet to an open-shell singlet in B4 (CO)2 and to a close-shell singlet in B4 (CO)3 , demonstrating that the electronic structures of boron clusters can be effectively tuned via sequential CO ligand coordination.

Ligand-Induced Tuning of the Electronic Structure of Rhombus Tetraboron Cluster.

Structural characterization of neutral water clusters is crucial to understanding the structures and properties of water, but it has been proven to be a challenging experimental target due to the difficulty in size selection. Here, we report the size-specific infrared spectra of confinement-free neutral water nonamer (H2O)9 based on threshold photoionization, using a tunable vacuum ultraviolet free-electron laser. Distinct OH stretch vibrational fundamentals in the 3200-3350 cm-1 region are observed, providing unique spectral signatures for the formation of an unprecedented (H2O)9 structure evolved by adding a ninth water molecule onto a hydrogen bond-unbroken edge of the (H2O)8 octamer with D2d symmetry. This nonamer structure coexists with the five previously identified structures that can be viewed as derived by inserting a ninth water molecule into a hydrogen bond-broken edge of the D2d/S4 octamer. These findings provide key microscopic information for systematic understanding of the formation and growth mechanism of dynamical hydrogen-bonding networks that are responsible for the structure and properties of condensed-phase water.

Spectroscopic snapshot for neutral water nonamer (H2O)9: Adding a H2O onto a hydrogen bond-unbroken edge of (H2O)8.

Investigation of the reactions between water molecules and neutral metal clusters is important in water splitting but is very challenging due to the inherent difficulty of size selection. Here, we report a size-specific infrared-vacuum ultraviolet spectroscopic study on the reactions of water with neutral vanadium dimer. The V2O3H4 and V2O4H6 products were characterized to have unexpected V2(μ2-OH)(μ2-H)(η1-OH)2 and V2(μ2-OH)2(η1-H)2(η1-OH)2 structures, indicative of a water decomposition. A combination of theory and experiment reveals that the water splitting by V2 is both thermodynamically exothermic and kinetically facile in the gas phase. The present system serves as a model for clarifying the pivotal roles played by neutral metal clusters in water decomposition and also opens new avenues toward systematic understanding of water splitting by a large variety of single-cluster catalysts.

W. H. Yan

Papers

Reinvestigation of the collective band structures in odd-odd 138Pm nucleus

Ligand-Induced Tuning of the Electronic Structure of Rhombus Tetraboron Cluster.

Spectroscopic snapshot for neutral water nonamer (H2O)9: Adding a H2O onto a hydrogen bond-unbroken edge of (H2O)8.

Size-Specific Infrared Spectroscopic Study of the Reactions between Water Molecules and Neutral Vanadium Dimer: Evidence for Water Splitting.

Spectroscopic identification of water splitting by neutral group 3 metals