Sulfate radical-based advanced oxidation processes (SR-AOPs) employing heterogeneous catalysts to generate sulfate radical (SO4 −) from peroxymonosulfate (PMS) and persulfate (PS) have been extensively employed for organic contaminant removal in water. This article aims to provide a state–of–the–art review on the recent development in heterogeneous catalysts including single metal, mixed metal, and nonmetal carbon catalysts for organic contaminants removal, with particular focus on PMS activation. The hybrid heterogeneous catalyst/PMS systems integrated with other advanced oxidation technologies is also discussed. Several strategies for the identification of principal reactive radicals in SO4 −–oxidation systems are evaluated, namely (i) use of chemical probe or spin trapping agent coupled with analytical tools, and (ii) competitive kinetic approach using selective radical scavengers. The main challenges and mitigation strategies pertinent to the SR-AOPs are identified, which include (i) possible formation of oxyanions and disinfection byproducts, and (ii) dealing with sulfate produced and residual PMS. Potential future applications and research direction of SR-AOPs are proposed. These include (i) novel reactor design for heterogeneous catalytic system based on batch or continuous flow (e.g. completely mixed or plug flow) reactor configuration with catalyst recovery, and (ii) catalytic ceramic membrane incorporating SR-AOPs.

Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: Current development, challenges and prospects

Water purification using magnetic assistance: a review.

http://jalal30.persiangig.com/image/1-s2.0-S0304389410006722-main.pdf

Simultaneous removal of heavy-metal ions in wastewater samples using nano-alumina modified with 2,4-dinitrophenylhydrazine.

Industrial wastewater polluted with various contaminants, including heavy metals, dyes, etc., endangers human health and the environment. Various separation techniques have been developed for the removal of pollutants from aqueous solutions. Adsorption process has drawn considerable attention due to its simplicity of design, high removal efficiency, even at dilute concentration, and economical aspect. We reviewed the most common two, three, four, and five parameter adsorption isotherm models corresponding to monolayer and multilayer adsorption on the basis of parameters that can be used for exploring novel adsorbents. Thermodynamic assumptions of the models give information about the surface properties, capacity of the adsorbent and adsorption mechanism. Seven error functions were investigated to evaluate the fitness quality of isotherm models with the experimental equilibrium data.

/pdf/monolayer-and-multilayer-adsorption-isotherm-models-for-19r6dsml0t.pdf

Monolayer and multilayer adsorption isotherm models for sorption from aqueous media

Adsorption is widely popular for removal of heavy metals due to its low cost, efficiency, and simplicity. The focus of this review will be the use of inorganic adsorbents engineered at the nanoscale. The applicability of iron oxide (hematite, magnetite and maghemite), carbon nanotubes (CNT), and metal oxide based (Ti, Zn) and polymeric nanoadsorbents are examined. The advantages and limitations of the type of nanoadsorbent and its functionality are evaluated. Current developments and next generation adsorbents are also reviewed. Finally, scopes and limitations of these adsorbents will be addressed while investigating the types of metal ions that are harmful.

https://pubs.rsc.org/en/content/articlepdf/2015/ra/c5ra02714d

Inorganic nano-adsorbents for the removal of heavy metals and arsenic: a review

Removal of lead, copper, nickel, cobalt, and zinc from water by a cancrinite-type zeolite synthesized from fly ash

Study on a novel POM-based magnetic photocatalyst: Photocatalytic degradation and magnetic separation

Tuning Structures of Pt Shells on Pd Nanocubes as Neutral Glucose Oxidation Catalysts and Sensors

The single-factor experiments are designed to quantitatively investigate the effects of silica fume, mineral powder, and fly ash on the mechanical and thermal insulation properties of desulfurization gypsum-based composites (DGCs). The effect mechanism is discussed from the microscopic morphology of the internal structure, and the corresponding relationship between the strength and thermal conductivity of this material is evaluated by the regression model. The results show that the admixture of silica fume, mineral powder, and fly ash improves the strengths and thermal insulation properties of DGCs, with the order of influence silica fume > mineral powder > fly ash. The optimal 28 d compressive strength and thermal conductivity are 34.17 MPa and 0.2146 W/(m·K), respectively, at a silica fume dosage of 35%. The enhancement effects on the strength and thermal insulation performance of DGCs are attributed to the increase in the hydration products C-S-H gel and Aft. Moreover, the thermal conductivity linearly decreases with the increase in the compressive strength of DGC after adding silica fume, mineral powder, and fly ash. The linear regression models exhibit good precision for evaluating the corresponding relationships between the compressive strength and thermal conductivity of DGCs with different admixtures.

/pdf/effects-of-different-admixtures-on-the-mechanical-and-3m6quahh.pdf

Wei Qiu

Papers

Removal of lead, copper, nickel, cobalt, and zinc from water by a cancrinite-type zeolite synthesized from fly ash

Study on a novel POM-based magnetic photocatalyst: Photocatalytic degradation and magnetic separation

Tuning Structures of Pt Shells on Pd Nanocubes as Neutral Glucose Oxidation Catalysts and Sensors

Effects of Different Admixtures on the Mechanical and Thermal Insulation Properties of Desulfurization Gypsum-Based Composites

Phase transition and ionic conduction enhancement induced by co-doping of LiI and MnI2 in a one-dimensional lead iodide perovskite.