Showing papers by "Wei Wang published in 2006"
TL;DR: The reaction of phenols and dihydroxybenzenes with epoxide in the presence of nano CaCO3 was studied in this paper, where the authors attributed the strong interaction between nano caCO3 and the substrate as catechol possessed intrahydrogen bond and excess active hydrogen, which can induce the intramolecular proton transfer via the intra-olecular hydrogen bond and promote the reaction of hydroxyl and epoxide.
Abstract: The reaction of phenols and dihydroxybenzenes with epoxide in the presence of nano CaCO3 was studied. Catechol could react with epoxide and gave monochlorohydrin derivative; other dihydroxybenzenes and monomeric phenols had no reaction under the same conditions. The reaction of catechol with epoxide did not occur when nano CaCO3 was replaced by a normal one. These were attributed to the strong interaction between nano CaCO3 and the substrate as catechol possessed intrahydrogen bond and excess active hydrogen, which can induce the intramolecular proton transfer via the intramolecular hydrogen bond and promote the reaction of hydroxyl and epoxide. This is an example revealing the unique role of the hydrogen bond played in chemical reactions.
3 citations