As a fascinating conjugated polymer, graphitic carbon nitride (g-C3N4) has become a new research hotspot and drawn broad interdisciplinary attention as a metal-free and visible-light-responsive photocatalyst in the arena of solar energy conversion and environmental remediation. This is due to its appealing electronic band structure, high physicochemical stability, and “earth-abundant” nature. This critical review summarizes a panorama of the latest progress related to the design and construction of pristine g-C3N4 and g-C3N4-based nanocomposites, including (1) nanoarchitecture design of bare g-C3N4, such as hard and soft templating approaches, supramolecular preorganization assembly, exfoliation, and template-free synthesis routes, (2) functionalization of g-C3N4 at an atomic level (elemental doping) and molecular level (copolymerization), and (3) modification of g-C3N4 with well-matched energy levels of another semiconductor or a metal as a cocatalyst to form heterojunction nanostructures. The constructi...

Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability?

Worldwide commercial interest in carbon nanotubes (CNTs) is reflected in a production capacity that presently exceeds several thousand tons per year. Currently, bulk CNT powders are incorporated in diverse commercial products ranging from rechargeable batteries, automotive parts, and sporting goods to boat hulls and water filters. Advances in CNT synthesis, purification, and chemical modification are enabling integration of CNTs in thin-film electronics and large-area coatings. Although not yet providing compelling mechanical strength or electrical or thermal conductivities for many applications, CNT yarns and sheets already have promising performance for applications including supercapacitors, actuators, and lightweight electromagnetic shields.

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Carbon Nanotubes: Present and Future Commercial Applications

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries

The science and technology of ultracapacitors are reviewed for a number of electrode materials, including carbon, mixed metal oxides, and conducting polymers. More work has been done using microporous carbons than with the other materials and most of the commercially available devices use carbon electrodes and an organic electrolytes. The energy density of these devices is 3¯5 Wh/kg with a power density of 300¯500 W/kg for high efficiency (90¯95%) charge/discharges. Projections of future developments using carbon indicate that energy densities of 10 Wh/kg or higher are likely with power densities of 1¯2 kW/kg. A key problem in the fabrication of these advanced devices is the bonding of the thin electrodes to a current collector such the contact resistance is less than 0.1 cm2. Special attention is given in the paper to comparing the power density characteristics of ultracapacitors and batteries. The comparisons should be made at the same charge/discharge efficiency.

Ultracapacitors: Why, How, and Where is the Technology

Energy-storage technologies, including electrical double-layer capacitors and rechargeable batteries, have attracted significant attention for applications in portable electronic devices, electric vehicles, bulk electricity storage at power stations, and “load leveling” of renewable sources, such as solar energy and wind power. Transforming lithium batteries and electric double-layer capacitors requires a step change in the science underpinning these devices, including the discovery of new materials, new electrochemistry, and an increased understanding of the processes on which the devices depend. The Review will consider some of the current scientific issues underpinning lithium batteries and electric double-layer capacitors.

Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors

It is estimated that the world will need to double its energy supply by 2050. Nanotechnology has opened up new frontiers in materials science and engineering to meet this challenge by creating new materials, particularly carbon nanomaterials, for efficient energy conversion and storage. Comparing to conventional energy materials, carbon nanomaterials possess unique size-/surface-dependent (e.g., morphological, electrical, optical, and mechanical) properties useful for enhancing the energy-conversion and storage performances. During the past 25 years or so, therefore, considerable efforts have been made to utilize the unique properties of carbon nanomaterials, including fullerenes, carbon nanotubes, and graphene, as energy materials, and tremendous progress has been achieved in developing high-performance energy conversion (e.g., solar cells and fuel cells) and storage (e.g., supercapacitors and batteries) devices. This article reviews progress in the research and development of carbon nanomaterials during the past twenty years or so for advanced energy conversion and storage, along with some discussions on challenges and perspectives in this exciting field.

Carbon Nanomaterials for Advanced Energy Conversion and Storage

https://case.edu/cse/eche/daigroup/Journal%20Articles/2009/Lu-2009-High%20Performance.pdf

High performance electrochemical capacitors from aligned carbon nanotube electrodes and ionic liquid electrolytes

We report a new class of nanocomposite electrodes for the development of high-performance supercapacitors with environmentally friendly ionic liquid electrolytes. Having the high-surface-area activated carbons, carbon nanotubes, and ionic liquids as integrated constituent components, the resultant composites show significantly improved charge storage and delivery capabilities. In an ionic liquid electrolyte, the composites possess a superior capacitance (188 F/g) over a pure carbon nanotube electrode (20 F/g) and a conventional activated carbon electrode (90 F/g). On the basis of these nanocomposite electrodes and an ionic liquid electrolyte, we have further developed prototype supercapacitors with a high cell voltage (4 V) and superior energy and power densities (50 Wh/kg and 22 kW/kg, respectively, in terms of the mass of the active electrode material). The nanocomposite supercapacitors developed in the present study clearly outperform the current supercapacitor technology, providing a new approach in f...

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Nanocomposite Electrodes for High-Performance Supercapacitors

The rapid development in wearable electronics has spurred a great deal of interest in flexible energy storage devices, particularly fiber-shaped energy storage devices (FSESDs), such as fiber-shaped supercapacitors (FSSCs) and fiber-shaped batteries (FSBs). Depending on their electrode configurations, FSESDs can contain five differently structured electrodes, including parallel fiber electrodes (PFEs), twisted fiber electrodes (TFDs), wrapped fiber electrodes (WFEs), coaxial fiber devices (CFEs), and rolled electrodes (REs). Various rational methods have been devised to incorporate these fiber-shaped electrodes into multifunctional FSESDs, including fiber-shaped supercapacitors, lithium-ion batteries, lithium-sulfur batteries, lithium-air batteries, zinc-air batteries, and aluminum-air batteries. Although significant progress has been made in FSESDs, it remains a major challenge to make high-performance fiber-shaped devices at low cost. A focused and critical review of the recent advancements in fiber-shaped supercapacitors and lithium-ion batteries is provided here. The pros and cons for each of the aforementioned electrode configurations and FSESDs are discussed, along with current challenges and future opportunities for FSESDs.

Wen Lu

Papers

Carbon Nanomaterials for Advanced Energy Conversion and Storage

High performance electrochemical capacitors from aligned carbon nanotube electrodes and ionic liquid electrolytes

Nanocomposite Electrodes for High-Performance Supercapacitors

Recent Advances in Fiber-Shaped Supercapacitors and Lithium-Ion Batteries

Boosting the supercapacitor performances of activated carbon with carbon nanomaterials