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Xiaohong Huo
Researcher at Shanghai Jiao Tong University
Publications - 31
Citations - 1916
Xiaohong Huo is an academic researcher from Shanghai Jiao Tong University. The author has contributed to research in topics: Enantioselective synthesis & Allylic rearrangement. The author has an hindex of 16, co-authored 24 publications receiving 1022 citations.
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An Ir/Zn Dual Catalysis for Enantio- and Diastereodivergent α-Allylation of α-Hydroxyketones.
TL;DR: An Ir/Zn dual catalysis has been developed for the enantio- and diastereodivergent α-allylation of unprotected α-hydroxyketones under mild conditions, in the absence of any additional base.
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Ir/Cu Dual Catalysis: Enantio- and Diastereodivergent Access to α,α-Disubstituted α-Amino Acids Bearing Vicinal Stereocenters
TL;DR: A fully stereodivergent synthesis of a range of α,α-disubstituted α-amino acids via an Ir/Cu-catalyzed α-allylation of readily available imine esters is described, affording all stereoisomers of the desired products.
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Asymmetric synthesis of allylic compounds via hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes.
TL;DR: An overview of hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes is provided, and the chiral ligand used in this area of research is summarized.
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Stereoselective and Site-Specific Allylic Alkylation of Amino Acids and Small Peptides via a Pd/Cu Dual Catalysis
TL;DR: A direct and highly stereoselective synthesis of small peptides with enantiopure α-alkyl or α,α-dialkyl α-amino acids residues incorporated at specific sites was accomplished using this dual catalyst system.
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Palladium‐Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study
TL;DR: A computational study suggested that methanol plays a crucial role in the formation of the π-allylpalladium complex by lowering the activation barrier.