Recovery and reuse of expensive catalysts after catalytic reactions are important factors for sustainable process management. The aim of this Review is to highlight the progress in the formation and catalytic applications of magnetic nanoparticles and magnetic nanocomposites. Directed functionalization of the surfaces of nanosized magnetic materials is an elegant way to bridge the gap between heterogeneous and homogeneous catalysis. The introduction of magnetic nanoparticles in a variety of solid matrices allows the combination of well-known procedures for catalyst heterogenization with techniques for magnetic separation.

Magnetically Separable Nanocatalysts: Bridges between Homogeneous and Heterogeneous Catalysis

Emulsions stabilized with solid nanoparticles: Pickering emulsions

In this Review, we aim to provide an updated summary of the research related to hollow micro- and nanostructures, covering both their synthesis and their applications. After a brief introduction to the definition and classification of the hollow micro-/nanostructures, we discuss various synthetic strategies that can be grouped into three major categories, including hard templating, soft templating, and self-templating synthesis. For both hard and soft templating strategies, we focus on how different types of templates are generated and then used for creating hollow structures. At the end of each section, the structural and morphological control over the product is discussed. For the self-templating strategy, we survey a number of unconventional synthetic methods, such as surface-protected etching, Ostwald ripening, the Kirkendall effect, and galvanic replacement. We then discuss the unique properties and niche applications of the hollow structures in diverse fields, including micro-/nanocontainers and rea...

Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures

Colloidal synthesis offers a route to nanoparticles (NPs) with controlled composition and structural features. This Perspective describes the use of polyvinylpyrrolidone (PVP) to obtain such nanostructures. PVP can serve as a surface stabilizer, growth modifier, nanoparticle dispersant, and reducing agent. As shown with examples, its role depends on the synthetic conditions. This dependence arises from the amphiphilic nature of PVP along with the molecular weight of the selected PVP. These characteristics can affect nanoparticle growth and morphology by providing solubility in diverse solvents, selective surface stabilization, and even access to kinetically controlled growth conditions. This Perspective includes discussions of the properties of PVP-capped NPs for surface enhanced Raman spectroscopy (SERS), assembly, catalysis, and more. The contribution of PVP to these properties as well as its removal is considered. Ultimately, the NPs accessed through the use of PVP in colloidal syntheses are opening new applications, and the concluding guidelines provided herein should enable new nanostructures to be accessed facilely.

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Polyvinylpyrrolidone (PVP) in nanoparticle synthesis

This article reports on the International Nanofluid Property Benchmark Exercise, or INPBE, in which the thermal conductivity of identical samples of colloidally stable dispersions of nanoparticles or “nanofluids,” was measured by over 30 organizations worldwide, using a variety of experimental approaches, including the transient hot wire method, steady-state methods, and optical methods. The nanofluids tested in the exercise were comprised of aqueous and nonaqueous basefluids, metal and metal oxide particles, near-spherical and elongated particles, at low and high particle concentrations. The data analysis reveals that the data from most organizations lie within a relatively narrow band (±10% or less) about the sample average with only few outliers. The thermal conductivity of the nanofluids was found to increase with particle concentration and aspect ratio, as expected from classical theory. There are (small) systematic differences in the absolute values of the nanofluid thermal conductivity among the various experimental approaches; however, such differences tend to disappear when the data are normalized to the measured thermal conductivity of the basefluid. The effective medium theory developed for dispersed particles by Maxwell in 1881 and recently generalized by Nan et al. [J. Appl. Phys. 81, 6692 (1997)], was found to be in good agreement with the experimental data, suggesting that no anomalous enhancement of thermal conductivity was achieved in the nanofluids tested in this exercise.

A Benchmark Study on the Thermal Conductivity of Nanofluids

In this technical note we develop an adaptive tuned vibration absorber (ATVA) based on the unique characteristics of magnetorheological elastomers (MREs), whose modulus can be controlled by an applied magnetic field. The MRE used in the developed ATVA was prepared by curing a mixture of 704 silicon rubber, carbonyl iron particles and a small amount of silicone oil under a magnetic field. The ATVA works in shear mode and consists of an oscillator, smart spring elements with MREs, a magnet conductor and two coils. Natural frequencies of the ATVA under different magnetic fields were both theoretically analyzed and experimentally evaluated by employing a beam structure with two ends supported. The experimental results demonstrated that the natural frequency of the ATVA can be tuned from 55 to 82 Hz. The relative frequency change is as high as 147%. Furthermore, the absorption capacity of the developed ATVA can achieve as high as 60 dB, which was also experimentally justified.

https://iopscience.iop.org/article/10.1088/0964-1726/15/5/N02/pdf

Development of an adaptive tuned vibration absorber with magnetorheological elastomer

Fabrication and characterization of isotropic magnetorheological elastomers

Well-defined magnetic separable, hollow spherical Fe3O4/TiO2 hybrid photocatalysts were successfully prepared through a poly(styrene−acrylic acid) (PSA) template method. This bifunctional product was characterized in terms of the particle size, surface morphology, chemical composition, and magnetic properties using transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), and X-ray powder diffraction (XRD) patterns. The M−H hysteresis loop for Fe3O4/TiO2 hollow spheres indicates that the composite spheres show superparamagnetic characteristics at room temperature. These magnetic TiO2 composites with hollow nature exhibit good photocatalytic activity under UV light irradiation and can be recycled six times by magnetic separation without major loss of activity. This method can be further applied to synthesize other bifunctional hollow spheres, such as Fe3O4/SnO2 and Fe3O4/CdS.

Magnetically Separable Fe3O4/TiO2 Hollow Spheres: Fabrication and Photocatalytic Activity

Magnetorheological Elastomers (MR Elastomers or MREs) are a kind of novel smart material, whose mechanical, electrical, magnetic properties are controllable under applied magnetic fields. They have attracted increasing attentions and broad application prospects. But conventional MREs are limited to wide applications because their MR effects and mechanical performances are not high enough. This paper aims to optimize the fabrication method and to fabricate good natural rubber based MREs with high modulus by investigating the influences of a variety of fabrication conditions on the MREs performances, such as matrix type, external magnetic flux density, and temperature, plasticizer and iron particles. Among these factors, the content of iron particles plays a most important contribution in shear modulus. When the iron particle weight fraction is 80% and the external magnetic flux density is 1 T, the field-induced increment of shear modulus reaches 3.6 MPa, and the relative MR effect is 133%. If the iron weight fraction increases to 90%, the field-induced increment of shear modulus is 4.5 MPa. This result has exceeded the best report in the literatures researching the MREs on the same kind of matrix. The dynamic performances of MREs were also experimentally characterized by using a modified Dynamic Mechanical Analyzer (DMA) system. The effects of strain amplitude and driving frequency on viscoelastic properties of MREs were analyzed.

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Investigation on magnetorheological elastomers based on natural rubber

The microstructures and viscoelastic properties of anisotropic magnetorheological elastomers are investigated. The measurement results show that their mechanical properties are greatly dependent on the magnetic flux density applied during preparation. A finite-column model is proposed to describe the relationships between the microstructures and the viscoelastic properties. The simulation results agree well with the experimental results.

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Xinglong Gong

Papers

Development of an adaptive tuned vibration absorber with magnetorheological elastomer

Fabrication and characterization of isotropic magnetorheological elastomers

Magnetically Separable Fe3O4/TiO2 Hollow Spheres: Fabrication and Photocatalytic Activity

Investigation on magnetorheological elastomers based on natural rubber

Microstructures and viscoelastic properties of anisotropic magnetorheological elastomers