Nitrate is an increasingly important component of fine particulate matter (PM2.5) during winter in northern China. Past emission control has been ineffective in reducing winter nitrate. Here, we use extensive observations and a model with state-of-the-art nitrogen chemistry to identify the key factors that control the nitrate formation in the heavily polluted North China Plain (NCP). In contrast to the previous view of weak winter photochemistry, we show that the O3 and OH productions are sufficiently high in winter to facilitate fast gas-phase and heterogeneous conversion of NOX to nitrate over the NCP. Increasing O3 and OH productions from higher precursor levels and fast ROX cycling accelerate the nitrate generation during heavy pollution. We find that the 31.8% reduction of NOX emissions from 2010 to 2017 in the NCP lowers surface nitrate by only 0.2% and even increases nitrate in some polluted areas. This is mainly due to the increase of O3 and OH (by ∼30%), which has subsequently increased the conversion efficiency of NOX to HNO3 (by 38.7%). Future control strategies for the winter haze should also aim to lower photochemical oxidants, via larger and synchronized NOX and VOCs emissions reduction, to overcome the effects of nonlinear photochemistry and aerosol chemical feedback.

Persistent Heavy Winter Nitrate Pollution Driven by Increased Photochemical Oxidants in Northern China.

Increasing importance of nitrate formation for heavy aerosol pollution in two megacities in Sichuan Basin, southwest China.

Regional differences in spatial spillover and hysteresis effects: A theoretical and empirical study of environmental regulations on haze pollution in China

The unprecedented slowdown in China during the COVID-19 period of November 2019 to April 2020 should have reduced pollution in smog-laden cities. However, moderate resolution imaging spectrometer (MODIS) satellite retrievals of aerosol optical depth (AOD) show a marked increase in aerosols over the Beijing–Tianjin–Hebei (BHT) region and most of Northeast and Central China, compared with the previous winter. Fine particulate (PM2.5) data from ground monitoring stations show an increase of 19.5% in Beijing during January and February 2020, and no reduction for Tianjin. In March and April 2020, a different spatial pattern emerges, with very high AOD levels observed over 50% of the Chinese mainland, and including peripheral regions in the northwest and southwest. At the same time, ozone monitoring instrument (OMI) satellite-derived NO2 concentrations fell drastically across China. The increase in PM2.5 while NO2 decreased in BTH and across China is likely due to enhanced production of secondary particulates. These are formed when reductions in NOx result in increased ozone formation, thus increasing the oxidizing capacity of the atmosphere. Support for this explanation is provided by ground level air quality data showing increased volume of fine mode aerosols throughout February and March 2020, and increased levels of PM2.5, relative humidity (RH), and ozone during haze episodes in the COVID-19 lockdown period. Backward trajectories show the origin of air masses affecting industrial centers of North and East China to be local. Other contributors to increased atmospheric particulates may include inflated industrial production in peripheral regions to compensate loss in the main population and industrial centers, and low wind speeds. Satellite monitoring of the extraordinary atmospheric conditions resulting from the COVID-19 shutdown could enhance understanding of smog formation and attempts to control it.

Air pollution scenario over China during COVID-19

Evidence for superiority of conventional adsorbents in the sorptive removal of gaseous benzene under real-world conditions: Test of activated carbon against novel metal-organic frameworks

Xuan Li

Papers

Secondary inorganic aerosols formation during haze episodes at an urban site in Beijing, China