Gibbs free energy of gaseous phosphorus dimer

Prediction of entropy and Gibbs free energy for nitrogen

Enthalpy of gaseous phosphorus dimer

We first report three reliable analytical expressions of the entropy, enthalpy and Gibbs free energy of carbon dioxide (CO2) and perform predictions of these three thermodynamic quantities on the basis of the proposed analytical expressions and in terms of experimental values of five molecular constants for CO2. The average relative deviations of the calculated values from the National Institute of Standards and Technology database over the temperature range from 300 to 6000 K are merely 0.053, 0.95, and 0.070%, respectively, for the entropy, enthalpy, and Gibbs free energy. The present predictive expressions are away from the utilization of plenty of experimental spectroscopy data and are applicable to treat CO2 capture and storage processes.

Thermodynamic Properties for Carbon Dioxide.

We obtained an approximate solution of the Schrodinger equation for the modified Kratzer potential plus screened Coulomb potential model, within the framework of Nikiforov–Uvarov method. The bound state energy eigenvalues for N2, CO, NO, and CH diatomic molecules were computed for various vibrational and rotational quantum numbers. Special cases were considered when the potential parameters were altered, resulting into modified Kratzer potential, screened Coulomb potential, and standard Coulomb potential, respectively. Their energy eigenvalues expressions and numerical computations agreed with the already existing literatures.

Yu Xiong

Papers

Predictions of entropy for diatomic molecules and gaseous substances

A reservoir drying method for enhancing recovery of tight gas