Zhenzhen Jiang

TL;DR: The development of porous metal-organic framework (MOF) solids displaying efficient separation and purification of acetylene is of cardinal significance but challenging in the chemical industry as discussed by the authors.

TL;DR: Stability studies showed that the cage-based MOF assembled from a tetranuclear Cu4O-based SBU and an amine-functionalized N,O-mixed donor ligand maintained its structural integrity after being immersed in HCl/NaOH aqueous solutions within a pH range of 4-11 at ambient temperature for 24 h, indicating its good hydrolytic stability under harsh chemical conditions, which might lay a solid foundation for its practical applications.

TL;DR: A comparative investigation demonstrated that N-oxide is a powerful chemical functionality that can be utilized to design and construct porous framework compounds for boosting C2H2 and CO2 adsorptions.

TL;DR: In this article, an aminopyridine-functionalized diisophthalate ligand was designed and synthesized by employing a ligand heterobifunctionalization strategy and successfully targeted its corresponding copper-based NbO-type MOF ZJNU-98.

TL;DR: In this article, a new MOF [Cu4L3Cl]Cl·2.7DMF (H2L = 5-(pyrimidine-5-yl)isophthalic acid, DMF = N,N-dimethylformamide) based on a heterotopic N,O-donor ligand was solvothermally constructed, featuring saturated metal centers as well as inorganic chloride ions immobilized in the aromatic cage surface.