Showing papers by "École nationale supérieure de chimie de Lille published in 1994"
TL;DR: In this paper, a comparative study of a number of intumescent systems for commercial ethylene-vinyl acetate polymers and based on ammonium polyphosphate and polyol is presented.
40 citations
TL;DR: In this paper, the highest chemoselective synthesis of 4-vinylcyclohexene was achieved by butadiene cyclodimerization on nickel complexes with aminophosphinephosphinite and bis(aminophosphines) chiral ligands (selectivity up to 99%).
29 citations
17 citations
TL;DR: The reaction of Cr(CO) 3 -complexed chloroarenes with HCO 2 CH 3 and NaOCH 3 in the presence of a catalytic amount of PdCl 2 (PPh 3 ) 2 gives esters in good yields provided that the arene is substituted by an electron-donating group as discussed by the authors.
13 citations
TL;DR: In this article, the effects of the modification of cobalt carbonyl complexes on the double carbonylation of phenethyl bromide were studied and the best cobalt catalyst was found to be Co 2 (CO) 8 and the selectivity strongly depends on the nature of the phosphine.
12 citations
TL;DR: The rhodium-catalyzed hydroformylation of ortho -substituted tricarbonyl(η 6 -styrene)-chromium occur with high regio- and diastereo selectivities as mentioned in this paper.
3 citations
TL;DR: In this paper, the authors present an overview of catalytic reactions and fundamental investigations with the aim to rationalize the role of the Cr(CO) 3 moiety on some of the elementary steps of these reactions.
Abstract: The effect of the coordination of a tricarbonylchromium moiety to the aromatic ring of aryl chlorides in the activation toward oxidative addition of the CCl bond to zerovalent palladium complexes is described. It presents an overview of catalytic reactions and fundamental investigations with the aim to rationalizing the role of the Cr(CO) 3 moiety on some of the elementary steps of these reactions. This topic is divided according to the nature of the catalytic reactions involving the tricarbonyl (chloroarene) chromium complexes. Firstly, the results obtained during the cross-coupling reaction with nucleophilic reagents (copper acetylides, organostannanes) and the catalytic Heck olefination reaction are presented. Then, several carbonylation processes, such as hydrocarbonylation into aldehydes, mono- and double carbonylation into amides and α-oxo-amides, and finally alkoxycarbonylation into esters, are discussed. Particular attention is given to the catalytic and stoichiometric aspects of this last reaction.