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5c. PROGRAM ELEMENT NUMBER
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Journal ArticleDOI
Connecting chemical dynamics in gases and liquids.
TL;DR: Vibrational energy transfer studies are the most advanced of the investigations and demonstrate that it is possible to observe state-specific pathways of energy flow within a vibrationally excited molecule and into the surrounding solvent molecules.
Journal ArticleDOI
Femtosecond laser studies of the cis-stilbene photoisomerization reactions. The cis-stilbene to dihydrophenanthrene reaction
TL;DR: After optical excitation of cis-stilbene, ground state dihydrophenantrene is formed in 17 ps (hexadecane) via kinetically required intermediate(s) present during the first 300±200 fs.
Journal ArticleDOI
Vibrational relaxation of CH3I in the gas phase and in solution
TL;DR: The vibrational state structure suggests a model for the relaxation dynamics in which a fast component of IVR populates the states that are most strongly coupled to the initially excited C-H stretch overtone, regardless of the environment, and the remaining, weakly coupled states result in a secondary relaxation only in the absence of IET.
Journal ArticleDOI
Transient electronic absorption of vibrationally excited CH2I2: Watching energy flow in solution
TL;DR: In this paper, a model based on the temperature dependence of the electronic absorption coefficient describes the transient absorption well for all wavelengths, reflecting the initial redistribution of energy within the excited molecule and the subsequent transfer of energy from the vibrationally excited molecule into the solvent.
Journal ArticleDOI
CH2I2 fundamental vibrational relaxation in solution studied by transient electronic absorption spectroscopy
TL;DR: In this article, a state-specific relaxation to one or a few states coupled by low order interactions with the initially prepared state dominates the intramolecular vibrational energy redistribution.