Journal ArticleDOI
A comparison between electrons solvated in ammonia and water: The volume expansion
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In this article, the authors suggest that the large difference in volume expansion for the solvated electron in ammonia and water is due to the different intermolecular interactions in both liquids.About:
This article is published in Chemical Physics Letters.The article was published on 1974-05-01. It has received 2 citations till now. The article focuses on the topics: Solvated electron & Intermolecular force.read more
Citations
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Size-dependent reactivity in open shell metal-ion polar solvent clusters: spectroscopic probes of electronic-vibration coupling, oxidation and ionization
TL;DR: In this paper, the authors consider the spectroscopy and structure of clusters formed by stepwise addition of polar solvent molecules such as NH3, H2O, and CH3OH to effective one-electron chromophores that include the singlycharged alkaline earth cations Mg+, Ca+, and Sr+; atomic sodium; and the Rydberg molecule NH4.
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Ammonia cluster anions and their relationship to ammoniated (solvated) electrons: The photoelectron spectra of (NH3)n=41–1100−
TL;DR: In this paper, the negative ion photoelectron spectra of (NH3)n=41−1100−, recorded using 2.540 eV photons, was used to infer that ammoniated electrons were generated in solid ammonia environments.
References
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Journal ArticleDOI
Excess Electrons in Polar Solvents
TL;DR: In this paper, a structural model for localized excess electron states in polar solvents with particular reference to dilute metal ammonia solutions and to the hydrated electron was proposed, and the over-all energetic stability of these species was assessed by considering simultaneously the electronic energy and the medium rearrangement energy.
Journal ArticleDOI
X-ray study of solid ammonia
Ivar Olovsson,David H. Templeton +1 more
TL;DR: Ammonia and deutero-ammonia have been studied by single-crystal and powder x-ray methods as mentioned in this paper, and the space group is confirmed to be P2/sub 1/3.
Journal ArticleDOI
Hydrogen bonded dimers and polymers involving hydrogen fluoride, water, and ammonia
Peter A. Kollman,Leland C. Allen +1 more
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Determination of the Structure of Liquid Ammonia by X‐Ray Diffraction
R. F. Kruh,J. I. Petz +1 more
TL;DR: In this article, X-ray diffraction measurements show that in liquid ammonia each molecule is surrounded on the average by about 11 other molecules and that hydrogen-bonded approaches occur at a mean distance of 3.56 A, and that the short-range spectrum of intermolecular distances resembles that of crystalline ammonia.
Journal ArticleDOI
γ Radiolysis of Liquids at High Pressures. X. The Reaction H+OH - and the Partial Molal Volume of the Hydrated Electron
Robert R. Hentz,David W. Brazier +1 more
TL;DR: In this paper, it was shown that G(H2) is independent of pressure over the range 0−6.2 kbar in γ radiolysis of the following deaerated aqueous solutions at 23°C: (a) solutions with 0.001 M or 0.1 M hydroxide, isopropanol at concentrations in the range 9'×'10−4 M to 0.
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