Journal ArticleDOI
Absorption spectra and photochemical rearrangements of C10H12 radical cations in solid argon. Dicyclopentadiene, 1,3-bishomocubane, bicyclo[6.2.0]deca-2,4,6-triene, and decapentaene
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TLDR
In this paper, the cycle des radicaux cationiques pour donner le cation trans-decapentaene is described. Buttude detaillee et comparative des resultats.Abstract:
Etude detaillee et comparative des resultats. Interet particulier de l'ouverture du cycle des radicaux cationiques pour donner le cation trans-decapentaeneread more
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The cation radical vinylcyclobutane rearrangement
TL;DR: In this article, the cation radical vinylcyclobutane (VCB) rearrangement was studied and the intramolecularity of the reaction was clearly established and in four discrete systems preferred sr (suprafacial/retention) stereochemistry was observed.
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The theoretical reaction path for the cation radical vinylcyclobutance rearrangement: a concerted SR path
TL;DR: In this article, a reaction path calculation for the cation radical vinylcyclobutane rearrangement at the MP2/6-31G*/3-21G level is presented.
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Ultraviolet absorption spectra of all-trans-octatetraene and -decapentaene in solid argon
TL;DR: In this paper, the vibronic bands in argon matrix spectra are sharper than bands in glassy matrix spectras for all trans -octatetraene and -decapentaene in solid argon.
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Correlation contributions to the radical cation states of linear even polyenes: An open‐shell RHF‐CNDO/S(CI) analysis of the optical and photoelectron spectra
TL;DR: In this paper, the configuration interaction wave functions for the low-lying radical cation states of trans-butadiene, hexatriene, and octatetraene within the open-shell RHF-CNDO/S(CI) approach were calculated for the transbutadienes, Hexatrienes, and OCTATRAEN.