Open AccessJournal Article
An investigation on the kinetics and mechanism of the thermal decomposition of GAP
TLDR
In this article, the thermal decomposition of GAP was investigated by using DSC, TGA, pyrolysis-MS, TG-FTIR, insitu pyrotechnics-FT IR coupling techniques.Abstract:
The whole process of the thermal decomposition of GAP was investigated by using DSC, TGA, pyrolysis-MS, TG-FTIR, insitu pyrolysis-FTIR coupling techniques. With the thermal decomposition of GAP, N2,NH3,HCN,H2CCO,CO,CO2,C2H4 and HCHO are detected in gas phase by TG-DTG-FTIR and thermolysis-MS coupling techniques. Meanwhile, the -N3 groups disappear first and form (CH)R(NH)( imine) in condensed phase. Kinetic parametes of decomposition were obtained and possible thermal decomposition mechanisms were suggested.read more
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