Journal ArticleDOI
Catalytic oxidation: III. The mechanism of ethylene and propylene oxidation over supported rhodium and ruthenium
Noel W. Cant,W.Keith Hall +1 more
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In this article, the kinetics of ethylene and propylene oxidation over Rh and Ru supported on low area α-alumina were studied and found similar to those reported earlier for the same metals supported on high area silica.About:
This article is published in Journal of Catalysis.The article was published on 1971-09-01. It has received 32 citations till now. The article focuses on the topics: Olefin fiber & Acrolein.read more
Citations
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Journal ArticleDOI
The oxidation of CO and hydrocarbons over noble metal catalysts
TL;DR: In this paper, the authors studied the reaction kinetics of CO, C 3 H 6, 1-hexene, and toluene under excess O 2 and found that the olefin oxidation is strongly self-inhibited by HC and more than first-order in O 2, whereas the opposite was found for Rh.
Journal ArticleDOI
Catalytic oxidation: VI. Oxidation of labeled olefins over silver
Noel W. Cant,W.K. Hall +1 more
TL;DR: In this paper, the effects of substitution of deuterium for hydrogen in ethylene and propylene with 14C-labeled epoxides have been studied over a silver catalyst.
Journal ArticleDOI
The catalytic oxidation of propylene: VI. Mechanistic studies utilizing isotopic tracers
L.David Krenzke,George W. Keulks +1 more
TL;DR: In this paper, the mechanism of propylene oxidation has been investigated over well-characterized selective oxidation catalysts: Bi 2 Mo 3 O 12, Bi 2MoO 6, and Bi 3 FeMo 2 O 12.
Journal ArticleDOI
Crystallite size effects during the catalytic oxidation of propylene on Ptγ-Al2O3
Luis M. Carballo,Eduardo E. Wolf +1 more
TL;DR: In this article, the reaction kinetics and crystallite size effects during the catalytic oxidation of propylene on Pt γ-Al 2 O 3 were investigated in a reactor-chemisorption apparatus.
Book ChapterDOI
Selective Oxidation of Propylene
TL;DR: In this paper, the authors focus on a single aspect of selective hydrocarbon oxidation, the selective oxidation of propylene to acrolein, with the questions in mind, such as how is propylene activated? What is the nature of the reactive oxygen species?
References
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Journal ArticleDOI
Studies of the Hydrogen Held by Solids. VII. The Exchange of the Hydroxyl Groups of Alumina and Silica-Alumina Catalysts with Deuterated Methane
John G. Larson,W.Keith Hall +1 more
Journal ArticleDOI
Catalytic oxidation. II. Silica supported noble metals for the oxidation of ethylene and propylene
Noel W. Cant,W.Keith Hall +1 more
TL;DR: In this paper, the catalytic properties of C2H4 and C3H6 were investigated over silica-supported Pt, Pd, Ir, Ru, Ru and Rh.
Journal ArticleDOI
Oxidation of propylene by means of SnO2MoO3 catalysts: I. The effect of combining SnO2 and MoO3
TL;DR: In this article, it was found that SnO 2, contacted around 450 °C with a gas saturated with MoO 2 (OH) 2, sorbs MoO 3 (or a hydrated form) to its surface.
Journal ArticleDOI
Catalytic Oxidation of Propene
TL;DR: In this article, the mechanism of the vapour-phase catalytic oxidation of propene to acrolein has been investigated in the presence of carbon-13 and deuterium.
Related Papers (5)
Catalytic oxidation. IV. Ethylene and propylene oxidation over gold
Noel W. Cant,W.Keith Hall +1 more
Catalytic oxidation. II. Silica supported noble metals for the oxidation of ethylene and propylene
Noel W. Cant,W.Keith Hall +1 more
The catalytic oxidation of propylene: I. Evidence for surface initiated homogeneous reactions
Chelliah Daniel,George W. Keulks +1 more