Journal ArticleDOI
Catalytic synthesis of ethanol from CO and H2 under atmospheric pressure over pyrolysed rhodium carbonyl clusters on TiO2, ZrO2, and La2O3
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In this paper, C2-oxygenated compounds composed mainly of ethanol were catalytically produced from CO and H2 under atmospheric pressure over pyrolysed Rh carbonyl clusters dispersed on specific metal oxides such as TiO2, ZrO2 and La2O3.Abstract:
C2-oxygenated compounds composed mainly of ethanol were catalytically produced from CO and H2 under atmospheric pressure over pyrolysed Rh carbonyl clusters dispersed on specific metal oxides such as TiO2, ZrO2, and La2O3.read more
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Journal ArticleDOI
Status and prospects in higher alcohols synthesis from syngas
TL;DR: This review comprehensively overviews syngas-based higher alcohols synthesis in three main sections, highlighting the advances recently made and the challenges that remain open and stimulate upcoming research activities.
Journal ArticleDOI
Activity and Selectivity Trends in Synthesis Gas Conversion to Higher Alcohols
Andrew J. Medford,Andrew J. Medford,Adam C. Lausche,Frank Abild-Pedersen,Burcin Temel,Niels C. Schjødt,Jens K. Nørskov,Jens K. Nørskov,Felix Studt +8 more
TL;DR: In this article, a mean-field micro-kinetic model for the formation of ethanol via CHxCO coupling is used along with a descriptor-based analysis to gain insight into the fundamental factors determining activity and selectivity on transition-metal surfaces.
Journal ArticleDOI
Surface-supported metal cluster carbonyls. Chemisorption, decomposition and reactivity of Os3(CO)12, H2Os3(CO)10 and Os6(CO)18 supported on silica and alumina and the investigation of the fischer-tropsch catalysis with these systems
TL;DR: In this article, the structure of the covalent attachment of a cluster to a surface can be regarded as a model for the metal-support interaction which is frequently involved in heterogeneous catalysis.
Journal ArticleDOI
Olefins from Syngas
TL;DR: Although the chemical industry is at present in a depressed state, this situation need not be permanent as mentioned in this paper, and the volume of raw materials used by the industry is already gigantic, but will grow even larger when the industry revives.
Book ChapterDOI
Further Investigation on Metal-Support Interaction: TiO2, CeO2, SiO2 Supported Platinum Catalysts
TL;DR: In this article, the authors compare catalytic properties of Pt/TiO 2 and Pt/CeO 2 for hydrogen and CO chemisorption, hydrogenation of benzene, n-hexane reaction and demonstrate that the nature of the SMSI is not the same for the two systems.