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Ceramic composite coating material

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TLDR
In this paper, a method of making the coating includes sequentially depositing a metallic bond coat on the metal article, at least one MCrAlY/ceramic layer on the bond coat, and a ceramic composite top layer on MCrA/Ceramic layer.
Abstract
A ceramic coating for a metal article includes a metallic bond coat deposited on the metal article, at least one MCrAlY/ceramic layer deposited on the bond coat, and a ceramic composite top layer deposited on the MCrAlY/ceramic layer. The M in MCrAlY stands for Fe, Ni, Co, or a mixture of Ni and Co. The ceramic in the MCrAlY/ceramic layer comprises mullite, alumina, zircon, silimanite, sodium zirconium phosphate, fused silica, cordierite, aluminum titanate, or zirconia. The ceramic composite top layer comprises a ceramic matrix and at least one secondary phase. A method of making the coating includes sequentially depositing a metallic bond coat on the metal article, at least one MCrAlY/ceramic layer on the bond coat, and a ceramic composite top layer on the MCrAlY/ceramic layer.

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References
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Thermal barrier coating system

TL;DR: In this article, a high temperature oxidation resistant thermal barrier coating system for a nickel-, cobalt-, or iron-base alloy substrate was proposed, which consists of mixtures of cubic, tetragonal, and monoclinic phases.
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Ceramic thermal barrier coating with alumina interlayer

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