Journal ArticleDOI
Electrodimerization: II. Reduction mechanism of immonium cations
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TLDR
In this paper, it was shown that in a broad series of immonium salts, the mechanism of the reductive coupling is a purely radical one and that the reduction process offers a simple mechanistic example of electrodimerization since acidic impurities present do not influence significantly the first electron transfer process.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1970-07-01. It has received 56 citations till now. The article focuses on the topics: Cyclic voltammetry & Linear sweep voltammetry.read more
Citations
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Journal ArticleDOI
Linear sweep voltammetry: Kinetic control by charge transfer and/or secondary chemical reactions
Louis Nadjo,Jean-Michel Savéant +1 more
TL;DR: In this article, the formal kinetics of systems involving kinetics control by the initial charge transfer step and/or secondary chemical reactions are derived for the following reaction schemes: first order deactivation, consecutive dimerization, e.g. disproportionation.
Journal ArticleDOI
New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines.
TL;DR: This review aims to provide a concise overview of modern transition-metal catalyzed approaches to alkylamine synthesis and their functionalization.
Journal ArticleDOI
Linear sweep voltammetry—compensation of cell resistance and stability
D. Garreau,Jean-Michel Savéant +1 more
TL;DR: In this paper, the problem of cell resitance compensation with a system comprising a potentiostat, a current measurer and a positive feedback device is discussed in relation to stability in the case of linear sweep voltammetry.
Journal ArticleDOI
Multicomponent synthesis of tertiary alkylamines by photocatalytic olefin-hydroaminoalkylation
TL;DR: This olefin-hydroaminoalkylation process involves a visible-light-mediated reduction of in-situ-generated iminium ions to selectively furnish previously inaccessible alkyl-substituted α-amino radicals, which subsequently react with alkenes to form C(sp3)–C( sp3) bonds.
Journal ArticleDOI
Electrodimerization: VIII. Role of proton transfer reactions in the mechanism of electrohydrodimerization formal kinetics for voltammetric studies (linear sweep, rotating disc, polarography)
Louis Nadjo,Jean-Michel Savéant +1 more
TL;DR: In this paper, the role played by proton transfer reactions in the formal kinetics of electrohydrodimerization processes is discussed, and the effects of the protonations of the various basic species generated at the electrode or through solution electron transfers are considered successively.
References
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Direct Synthesis of Ternary Iminium Salts by Combination of Aldehydes or Ketones with Secondary Amine Salts1,2
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Synthetische Reaktionen von Dimethylformamid I. Allgemeine Synthese von β-Dialdehyden
Zdeněk Arnold,F. Šorm +1 more
Journal ArticleDOI
The polarographic behaviour of polymethinium salts
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Electrodimerization: VIII. Role of proton transfer reactions in the mechanism of electrohydrodimerization formal kinetics for voltammetric studies (linear sweep, rotating disc, polarography)
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