Journal ArticleDOI
Femtosecond real-time alignment in chemical reactions
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In this paper, the femtosecond real-time alignment in dissociation reactions is observed experimentally for HgI2 and ICN and the results are accounted for by the classical theory outlined here.About:
This article is published in Chemical Physics Letters.The article was published on 1989-07-21. It has received 59 citations till now. The article focuses on the topics: Femtosecond.read more
Citations
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Femtosecond real-time probing of reactions. IV. The reactions of alkali halides
TL;DR: In this article, the femtosecond transition-state spectroscopy (FTS) was used to explore the photodissociation dynamics of some alkali halides via the method of FTS.
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Reprint of: Femtosecond transition-state spectroscopy of iodine: From strongly bound to repulsive surface dynamics
TL;DR: In this paper, the femtosecond transition-state spectroscopy (FTS) was applied to molecular iodine and the real-time motion of wave packets prepared coherently in the bound B state was observed.
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Femtosecond laser observations of molecular vibration and rotation
TL;DR: In this article, the authors report real-time observations of ultrafast molecular vibrations and rotations using femtosecond laser pulses, where the system is prepared in the particular state(s) of interest by coherent excitation with an initial femtocond laser pulse, and the subsequent motions are probed with successive femto-cond pulses.
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Real-time clocking of bimolecular reactions : application to H+CO2
TL;DR: In this paper, an experimental methodology is described for the real-time clocking of elementary bimolecular reactions, i.e., timing the process of formation and decay of the collision complex.
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Laser excitation of electronic wave packets in rydberg atoms
Gernot Alber,Peter Zoller +1 more
TL;DR: In this article, the authors review recent theoretical and experimental work on laser-induced excitation of atomic Rydberg wave packets and discuss generation and detection of wave packets by short and/or intense laser pulses.
References
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Real-time femtosecond probing of "transition states" in chemical reactions
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Femtosecond real‐time observation of wave packet oscillations (resonance) in dissociation reactions
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Femtosecond real-time probing of reactions. I. The technique
TL;DR: Femtosecond transition-state spectroscopy (FTS) as discussed by the authors is a real-time technique for probing chemical reactions, which allows direct observation of a molecule in the process of falling apart or in the formation.
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Purely rotational coherence effect and time‐resolved sub‐Doppler spectroscopy of large molecules. II. Experimental
TL;DR: In this paper, a theoretical treatment and experimental study of the phenomenon termed purely rotational coherence are presented, which arises from the thermal averaging of many single molecule coherences, with respect to their dependences on molecular parameters (rotational constants, transition dipole directions) and experimental parameters (polarization directions and temperature).
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Femtosecond real‐time probing of reactions. II. The dissociation reaction of ICN
TL;DR: In this article, femtosecond transition-state spectroscopy (FTS) was used for real-time analysis of the dissociation reaction ICN*→[I⋅/CN]^(‡*)→I+CN, where the process of the I−CN bond breaking was clocked and the transition states of the reaction were observed in real time.