Formation of a novel .eta.3:.eta.4-1,2,3-trimethyl-4,5-dimethylenecyclopentenyl ligand by hydrogen abstraction from a permethylcyclopentadienyl group in permethyltitanocene carbyl and related systems
Johannes W. Pattiasina,Catharina E. Hissink,Jan L. de Boer,Auke Meetsma,Jan H. Teuben,Anthony L. Spek +5 more
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This article is published in Journal of the American Chemical Society.The article was published on 1985-12-01 and is currently open access. It has received 92 citations till now. The article focuses on the topics: Hydrogen atom abstraction & Ligand.read more
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Chelate Complexes of Cyclopentadienyl Ligands Bearing Pendant O-Donors†
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Reactivity of a Terminal Ti(IV) Imido Complex toward Alkenes and Alkynes: Cycloaddition vs C−H Activation
TL;DR: In this article, the reactivity of base-free titanium imido complex Cp*2TiNPh (1) (Cp* = pentamethylcyclopentadienyl) toward alkenes and alkynes was investigated.
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Disiloxanediolates and polyhedral metallasilsesquioxanes of the early transition metals and f-elements
Volker Lorenz,Axel Fischer,Stephan Gießmann,John W. Gilje,Yurii K. Gun'ko,Klaus Jacob,Frank T. Edelmann +6 more
TL;DR: In this paper, the first f-element compounds derived from tetraphenylsisiloxanediol were described, with special emphasis being placed on early transition metal and felement derivatives.
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Catalytic olefin oligomerization and polymerization with cationic group IV metal complexes [Cp*2MMe(THT)]+[BPh4]-, M = Ti, Zr and Hf
TL;DR: In this paper, the properties of complex [Cp∗2MMe(THT)]+[BPh4]− (THT = tetrahydrothiophene; M = Ti, Zr, Hf) have been synthesized and their properties with respect to olefin oligomerization and polymerization studied.
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Bifunctional Cyclopentadienyl Ligands in Organotransition Metal Chemistry
TL;DR: In this article, the coordination chemistry of cyclopentadienyl ligands that contain an additional coordination site appended to the ring-periphery by a covalent bridge Z, C5R4−Z-X or C5 R4+Z-L, is outlined.