Journal ArticleDOI
In situ investigations of the 3-methylthiophene polymer with attenuated total reflection fourier transform infrared spectroscopy
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This article is published in The Journal of Physical Chemistry.The article was published on 1984-02-01. It has received 81 citations till now. The article focuses on the topics: Attenuated total reflection & Fourier transform spectroscopy.read more
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Journal ArticleDOI
Simple construction of an infrared optically transparent thin-layer electrochemical cell: Applications to the redox reactions of ferrocene, Mn2(CO)10 and Mn(CO)3(3,5-di-t-butyl-catecholate)−
M. Krejčik,M. Daněk,F. Hartl +2 more
TL;DR: In this article, an alternative construction of the sandwich-type IR OTTLE cell is presented, where the working Au- or Pt-mesh, twinned Ag-wire reference and auxiliary electrodes are melt-sealed into a polyethylene spacer.
Journal ArticleDOI
In situ spectroelectrochemical characterization of poly(3,4-ethylenedioxythiophene)
C. Kvarnström,C. Kvarnström,Helmut Neugebauer,S. Blomquist,H.J. Ahonen,Jouko Kankare,A. Ivaska +6 more
TL;DR: In this paper, the effect of polymerization current density and monomer concentration on the formation of the film structure was studied with cyclic voltammetry, in situ UV-VIS-spectroelectrochemistry, electrochemical quartz crystal microbalance technique (EQCM), and in situ Fourier transform infrared (FTIR) spectroscopy using external and internal reflection techniques.
Book ChapterDOI
Electronically conducting polymers
TL;DR: The exciting new field of conducting polymers has been reviewed from the viewpoint of electrochemistry in this article, where the main topics treated are electropolymerization, the structure, and the charge storage mechanism.
Journal ArticleDOI
Poly mono-, bi- and trithiophene: effect of oligomer chain length on the polymer properties
TL;DR: In this article, a comparison of the electrical, electrochemical and spectroscopic properties of the resulting polymers reveals a steady decrease of their conjugation length as the chain length of the starting oligomer increases.
Journal ArticleDOI
Chemical synthesis and characterization of soluble poly(4,4'-dialkyl-2,2'-bithiophenes)
TL;DR: In this article, a chemical polymerization of 4,4′-dialkyl-2,2′-bithiophenes is reported, where the resulting soluble polymers can be cast from their chloroform solutions to give thin layers and free-standing films, which can be doped by electrochemical and chemical methods.
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