Intermediate level structure, quantum beats, and nuclear spin effects in the electronic relaxation of the 1B3u (nπ*) state of pyrazine

TLDR: The P(1) member of the rotational manifold of the 6a10 transition in the 1B3u(nπ) state of pyrazine shows intermediate level structure and quantum beats in its decay as discussed by the authors.

Abstract: The P(1) member of the rotational manifold of the 6a10 transition in the 1B3u (nπ) state of pyrazine shows intermediate level structure and quantum beats in its decay. The P(2) member already shows a fast component. The effect of nuclear spin on the relative magnitude of the fast component is shown by partial deuterium substitution.

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University of Groningen
Intermediate level structure, quantum beats, and nuclear spin effects in the electronic
relaxation of the 1B3u (nπ*) state of pyrazine
van der Meer, Barend J. ; Jonkman, Harry Th.; ter Horst, Gerard M. ; Kommandeur, Jan
Published in:
The Journal of Chemical Physics
DOI:
10.1063/1.443185
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Publication date:
1982
Link to publication in University of Groningen/UMCG research database
Citation for published version (APA):
van der Meer, B. J., Jonkman, H. T., ter Horst, G. M., & Kommandeur, J. (1982). Intermediate level
structure, quantum beats, and nuclear spin effects in the electronic relaxation of the 1B3u (nπ*) state of
pyrazine.
The Journal of Chemical Physics
,
76
(4), 2099-2100. https://doi.org/10.1063/1.443185
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