Journal ArticleDOI
Kinetics and mechanism of the ruthenium(III) chloride catalyzed oxidation of butan-2-ol and methyl-1-propanol by the hexacyanoferrate(III) ion in an aqueous alkaline medium
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This article is published in The Journal of Physical Chemistry.The article was published on 1977-06-01. It has received 41 citations till now. The article focuses on the topics: Ruthenium(III) chloride & Aqueous solution.read more
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Ru(III)-catalyzed oxidation of N-acetyl-L-cysteine by methylene blue in absence and in presence of Cu(II) in acidic medium: influence of solvent and morphology
TL;DR: The kinetic deviations of the reaction, explained by presuming the participation of a reactive form of the NAC molecule or its new conformational polymorph reported recently, indicate the regulatory influence of the morphology of nanoparticles.
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Alcohol oxidation catalysed by Ru(VI) in the presence of alkaline hexacyanoferrate(III)
F. J. Poblete,Pablo Corrochano +1 more
TL;DR: In this article, the reaction mechanism involved the oxidation of the alcohol by the catalyst, a process that occurs through the formation of a substrate-catalyst complex, and the decomposition of this complex yields Ru(IV) and a carbocation.
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Effect of cationic surfactant on Ru(III) catalyzed L‐glutamic acid oxidation by hexacyanoferrate(III)
TL;DR: In this article , the progression of the reaction has been inspected as a function of [OH−, ionic strength, [CTAB], [Ru3+], [Glu], [Fe(CN)63−], and temperature using the pseudo-first-order condition.
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Kinetics and Mechanism of the Ruthenium (III) Catalysed Oxidation of Some Aliphatic and Cyclic Ketones by Periodate Ion in Aqueous Alkaline Medium: A Novel Behaviour of Ruthenium (III)
Subas C. Pati,Markandeswar Panda +1 more
TL;DR: In this article, the reaction rate increases linearly following a nearly unit dependence on [OH−] at lower concentration of alkali and levels off after a particular [OH]- and the activation parameters have been evaluated.