Journal ArticleDOI
Matrix Raman studies of Bin(n ⩾ 2) molecules
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TLDR
In this article, the metal concentration dependence of the bismuth spectra was investigated and two progressions with ωe = 172 and 152 cm−1 were assigned to Bi2 and Bi4, respectively.About:
This article is published in Chemical Physics Letters.The article was published on 1981-02-01. It has received 28 citations till now. The article focuses on the topics: Raman spectroscopy & Ground state.read more
Citations
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Resonance Raman Spectroscopy, and Its Application to Inorganic Chemistry. New Analytical Methods (27)
TL;DR: Resonance Raman spectra are obtained when the wave number of the exciting radiation is close to, or coincident with, that of an electronic transition of the scattering species as mentioned in this paper.
Journal ArticleDOI
Spectroscopic studies of the jet-cooled copper trimer
TL;DR: In this paper, a gas phase spectroscopic study of copper trimer has been conducted and the spectrum fits well to a 2E″←2E′ transition of a D3h molecule with both states undergoing Jahn-Teller distortions.
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Reactions of Ground State and Electronically Excited Atoms of Main Group Elements: a Matrix Perspective
TL;DR: Comparison between Gas-Phase and Matrix Isolation Studies 4210 and Reaction Pathways 4202 A. Simple Addition Reactions 4204 B. Insertion 4205 C. Isomerization 4207 D. Decomposition 4208 IV.
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Raman spectra of matrix-isolated group IIIA dimers: Ga2, In2, Tl2
TL;DR: In this article, the Raman spectra of Ga, In and Tl molecules are measured in Ar and Kr matrices and the ground-state vibrational frequencies and anharmonicities are assigned.
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Photoelectron spectroscopy and electronic structure of clusters of the group V elements. I, Dimers
TL;DR: In this article, the HeI (584 A) high resolution photoelectron spectra of As+2, Sb+2 and Bi+2 have been obtained with a high temperature molecular beam source.
References
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Journal ArticleDOI
Optical properties of silver microcrystals prepared by means of the gas aggregation technique
H. Abe,W. Schulze,B. Tesche +2 more
TL;DR: In this article, spherical silver microcrystallites with mean diameters between 10 and 200 A have been prepared by gas aggregation techniques using argon gas in a dynamic flow system, and a small quantity of these crystallites were allowed to condense onto an umorphous carbon foil, which allowed a direct characterisation of the size distribution by evaluating the corresponding electron micrographs.
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Matrix Raman spectra of Ag2 and Ag3
TL;DR: In this paper, several Raman bands below about 220 cm −1 are found, and the two strongest, at 194 ± 0.5 cm − 1 and 120.5 ± 0.5 cm−1, could clearly be assigned to Ag 2 and Ag 3 respectively.
Journal ArticleDOI
Electronic states and molecular constants of Bi2
G. Gerber,H. P. Broida +1 more
TL;DR: In this paper, the potential energy curves of several electronic states of Bi2 have been calculated by the Rydberg-Klein-Rees method using molecular constants obtained from laser-excited photoluminescence.
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Laser photoluminescence of Bi2
TL;DR: In this article, Bismuth diatomic molecules are produced in an inert gas flow system and in a heat-pipe oven at pressures from 10−4 to 10 torr.
Journal ArticleDOI
Some new electronic states of matrix-isolated diatomic bismuth
TL;DR: In this paper, the absorption spectra of the diatomic bismuth molecule in argon matrices reveal three hitherto unreported electronic states with band system origins at 12 395, about 15 246, and about 17 736 cm−1.
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Laser fluorescence studies of metal clusters: Spectroscopy of molecular bismuth
V. E. Bondybey,J. H. English +1 more