Journal ArticleDOI
Mechanism of the oxidation of glyceraldehyde by molecular oxygen
L. M. Andronov,Z. K. Maizus +1 more
TLDR
In this paper, a mechanism of oxidation, explaining the experimentally observed ratio of the rates of accumulation of the products, was proposed; according to this mechanism, the basic direction of the reaction of the peroxide radical is its interaction with the carbonyl group of glyceraldehyde.Abstract:
1.
The intermediates in the oxidation of glyceraldehyde in aqueous medium are glycolic aldehyde and methylglyoxal, while the final products are glyceric, glycolic, acetic, and formic acids and carbon dioxide.
2.
A mechanism of oxidation, explaining the experimentally observed ratio of the rates of accumulation of the products, was proposed; according to this mechanism, the basic direction of the reaction of the peroxide radical is its interaction with the carbonyl group of glyceraldehyde.read more
Citations
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Journal ArticleDOI
Quasi-Homogeneous Oxidation of Glycerol by Unsupported Gold Nanoparticles in the Liquid Phase
Elżbieta Skrzyńska,Elżbieta Skrzyńska,Jamal Ftouni,Jamal Ftouni,Jean-Sébastien Girardon,Jean-Sébastien Girardon,Mickaël Capron,Mickaël Capron,Louise Jalowiecki-Duhamel,Louise Jalowiecki-Duhamel,Jean-François Paul,Jean-François Paul,Franck Dumeignil,Franck Dumeignil,Franck Dumeignil +14 more
TL;DR: A quasi-homogeneous solution of gold nanoparticles prepared by the Turkevich method was used as an unconventional catalyst in the oxidation of glycerol (GLY) in the liquid phase, achieving highest obtained conversion after 3 h of reaction at 100 °C under an oxygen atmosphere.
Journal ArticleDOI
Ethanol determination using pressure mobilization and free solution capillary electrophoresis by photo-oxidation assisted ultraviolet detection.
TL;DR: This work presents the first detection and quantification of ethanol using either a simple pressure mobilization set-up or CE, and it is shown that ethanol interferes with this photo-oxidation reaction.
Dissertation
Nanostructures hybrides Au/Semi-conducteur : investigation des effets plasmoniques en catalyse sous lumière visible
TL;DR: In this article, a photocatalyse plasmonique basee sur le transfert d’electrons entre une NPO and un semi-conducteur is proposed.
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