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Method for catalytically converting lignin into aromatic hydrocarbon by using two-step process

Zhao Chen, +1 more
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TLDR
In this article, a method for catalytically converting lignin into aromatic hydrocarbon by using a two-step process is presented, which comprises the steps of (a) hydrogenolysis on Lignin in a polar solvent under the actions of a hydrodepolymerization catalyst and hydrogen pressure to obtain a phenol and oil mixture; and (b) carrying out rotary evaporation on the phenol-and oil mixture obtained in the step (a), and carrying out hydrodeoxygenation reaction under the conditions of a HOG catalyst, a
Abstract
The invention discloses a method for catalytically converting lignin into aromatic hydrocarbon by using a two-step process. The method comprises the steps of (a) carrying out hydrogenolysis on lignin in a polar solvent under the actions of a hydrodepolymerization catalyst and hydrogen pressure to obtain a phenol and oil mixture; and (b) carrying out rotary evaporation on the phenol and oil mixture obtained in the step (a), and carrying out hydrodeoxygenation reaction under the conditions of a hydrodeoxygenation catalyst, a solvent, high temperature and low pressure to obtain an aromatic hydrocarbon product. The invention also provides the hydrodepolymerization catalyst and the hydrodeoxygenation catalyst. According to the method, the cheap lignin is used as a raw material and is efficiently converted into the aromatic hydrocarbon under a mild reaction condition by using the two-step process, so that the aromatic hydrocarbon serving as a product is high in economic value, the reaction process is environmental friendly, and the method has wide application prospect.

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References
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Patent

Method for preparing aromatic compound by catalytic hydrocracking of lignin

TL;DR: In this paper, a method for preparing an aromatic compound by direct catalytic cracking of lignin is described. But the method is not suitable for the high yield of the aromatic compound and mild reaction condition.
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Method for preparing high-quality gasoline from cracking biological oil

Chen Zhao
TL;DR: In this article, a method for preparing high-quality gasoline from cracking biological oil and related to the technical field of hydrocarbon fuel preparation is described, where crude biological oil, lignocellulose, xylogen, phenolic monomer derived from the xylgen or/and lignin of the xymogen, cellulose, and a furan compound derived from cellulose are used as raw materials.
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Method for preparing high-quality gasoline directly from lignin by one-pot process

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TL;DR: In this article, a method for preparing high-quality gasoline directly from lignin by a one-pot process is described, and the method belongs to the technical field of new energy resources.
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