Journal ArticleDOI
Nuclear Magnetic Resonance at High Pressure
TLDR
The principles of this technique are presented; its usefulness is illustrated by several specific examples of studies of molecular liquids, water, and supercritical dense fluids; and the promising future of high-resolution nuclear magnetic resonance spectroscopy at high pressure is indicated.Abstract:
Nuclear magnetic resonance relaxation measurements at high pressure provide unique information about the microscopic behavior of liquids. This article presents the principles of this technique; illustrates its usefulness by several specific examples of studies of molecular liquids, water, and supercritical dense fluids; and indicates the promising future of high-resolution nuclear magnetic resonance spectroscopy at high pressure with examples of studies of chemical exchange and homogeneous catalytic processes.read more
Citations
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Journal ArticleDOI
Dynamics on the Way to Forming Glass: Bubbles in Space-Time
David Chandler,Juan P. Garrahan +1 more
TL;DR: A theoretical perspective of the dynamics of glass-forming liquids and the glass transition is reviewed, a perspective developed during this past decade based on the structure of trajectory space, which is characterized in terms of dynamical heterogeneity, facilitation, and excitation lines.
Journal ArticleDOI
The effect of high pressure upon proteins and other biomolecules.
TL;DR: The conceptual framework employed in the interpretation of high pressure experiments is examined in the critical discussion of the knowledge of selected areas of present interest and likely future significance.
Journal ArticleDOI
Corresponding states of structural glass formers.
TL;DR: It is shown that the effects of attractive forces in numerical simulation of glass-forming liquids can be logically organized in terms of J and T(o), and analysis of experimental data for several systems suggests that J andT(o) are material properties.
Journal ArticleDOI
Structural study of supercritical water. I. Nuclear magnetic resonance spectroscopy
TL;DR: In this article, the authors measured the proton chemical shift of water at supercritical temperatures up to 400°C and densities of 0.19, 0.29, 0,41, 0.,49, and 0.60g/cm3.
Journal ArticleDOI
Corresponding States of Structural Glass Formers. II
TL;DR: In this paper, it was shown that the effects of attractive forces in numerical simulation of glass forming liquids can be logically organized in terms of $J$ and $T$ where J$ and T$ are material properties.
References
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Book
An introduction to the liquid state
TL;DR: The Pair Theory of Liquids - Equilibrium Properties is illustrated with examples of interatomic and intermolecular interactions as well as a model of the Dynamic Structure.
Journal ArticleDOI
Studies in Molecular Dynamics. VIII. The Transport Coefficients for a Hard-Sphere Fluid
TL;DR: In this article, the authors compared the predictions of the Enskog theory with the observed deviations from an exponentially decaying autocorrelation function for many mean collision times, indicating that highly collective effects must be involved.
Book
Homogeneous Catalysis: The Applications and Chemistry of Catalysis by Soluble Transition Metal Complexes
TL;DR: In this article, the authors present trends in homogeneous catalysis in industry, including the following: Oxidation of Olefins and Dienes, Polymerization and Oligomerization of Olin and Olin, and Hyper-Hybrid Additions.
Journal ArticleDOI
Rough hard sphere theory of the self‐diffusion constant for molecular liquids
TL;DR: In this paper, a simple theory based on a hard sphere model is used to calculate the self-diffusion constant and the shear viscosity of liquid carbon tetrachloride.
Journal ArticleDOI
Relaxation processes and chemical kinetics
TL;DR: The role of relaxation processes in determining the rates of activated events has long been a point of discussion in chemical physics as mentioned in this paper, and an expansion in powers of the damping constant g is developed.