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Journal ArticleDOI

Phase equilibria and critical phenomena in fluid (n-alkane + water) systems at high pressures and temperatures

TLDR
In this paper, phase equilibria of the second type are found in fluid (n-alkane + water) mixtures (gas + gas) of the first type.
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This article is published in Fluid Phase Equilibria.The article was published on 1983-01-01. It has received 53 citations till now. The article focuses on the topics: Critical point (thermodynamics).

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Citations
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Predicting the High-Pressure Phase Equilibria of Water + n-Alkanes Using a Simplified SAFT Theory with Transferable Intermolecular Interaction Parameters

TL;DR: In this paper, a simplified version of the SAFT equation of state, based on the thermodynamic perturbation theory of Wertheim, was used for associating fluids. But the authors did not consider the non-pherical nature of the alkanes.
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Prediction of the Salting-Out Effect of Strong Electrolytes on Water + Alkane Solutions

TL;DR: Galindo et al. as mentioned in this paper investigated the salting out of n-alkanes in water by strong electrolytes using an extension of the statistical associating fluid theory for attractive potentials of variable range which incorporates ionic interactions.
Journal ArticleDOI

Predicting the Phase Equilibria, Critical Phenomena, and Mixing Enthalpies of Binary Aqueous Systems Containing Alkanes, Cycloalkanes, Aromatics, Alkenes, and Gases (N2, CO2, H2S, H2) with the PPR78 Equation of State

TL;DR: In this article, the phase behavior of water/hydrocarbon mixtures in a wide range of concentrations, temperatures, and pressures is predicted using the PPR78 cubic equation of state (EoS).
Journal ArticleDOI

Phase behavior of Athabasca bitumen + water mixtures at high temperature and pressure

TL;DR: In this paper, the phase boundary and phase composition accuracy and precision were validated by reproducing phase diagrams for 1-methylnaphthalene + water and toluene+water mixtures available in the literature.
References
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Journal ArticleDOI

Phase equilibria and critical phenomena in fluid (n-hexane + water) at high pressures and temperatures

TL;DR: In this paper, phase equilibria in fluid (n -hexane + water) were measured in the temperature range 610 to 675 K and at pressures from 15 to 140 MPa.
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Verdampfungsgleichgewichte und kritische Kurven in den Systemen Äthan/Wasser und n‐Butan/Wasser bei hohen Drücken

TL;DR: In beiden systems, the kritische Kurve is unterbrochen as mentioned in this paper, and die kritischen Drucke steigen ausgehend monoton an, wendet sich dann wieder zu hoheren Temperaturen.
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Gas‐gas equilibrium: High pressure limits

TL;DR: In this paper, it is shown that these regions are generally bounded on the high pressure side by a three-phase region of the type solid-gas-gas, which results from the solidification of the less volatile component.
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