Journal ArticleDOI
Potentiometric determination of plutonium by argentic oxidation, ferrous reduction and dichromate titration.
J.L. Drummond,R.A. Grant +1 more
TLDR
A simple and rapid method is described for the routine determination of plutonium with a coefficient of variation of better than 0.2% to nitrate solutions containing a large amount of uranium; moderate amounts of iron, molybdenum, fluoride and phosphate do not interfere.About:
This article is published in Talanta.The article was published on 1966-03-01. It has received 68 citations till now. The article focuses on the topics: Potassium dichromate & Potentiometric titration.read more
Citations
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Journal ArticleDOI
Preparation and characterisation of Pu-pyrochlore: [La1−xPux]2 Zr2O7 (x=0–1)
TL;DR: In this paper, thermal and X-ray powder diffraction studies were carried out on mixtures of PuO2, ZrO2 and graphite and a new cubic phase with pyrochlore structure (a=1.0592 nm) was identified and characterised.
Journal ArticleDOI
Studies on preparation of (U0.47,Pu0.53)O2 microspheres by internal gelation process
Ashok Kumar,J. Radhakrishna,Niteen Kumar,Rajesh V. Pai,J.V. Dehadrai,A.C. Deb,Subroto Mukerjee +6 more
TL;DR: In this article, an optimization of the internal gelation process was described to produce dense sintered (U0.47,Pu0.53)O2 microspheres.
Journal ArticleDOI
Indirect potentiometric method for the determination of plutonium.
Journal ArticleDOI
Solid state reactions of CeO2, ThO2 and PuO2 with ammonium sulphate
TL;DR: In this article, solid state reactions of CeO 2, ThO 2 and PuO 2 with (NH 4 ) 2 SO 4 were investigated by chemical, IR, thermal and X-ray diffraction methods.
Journal ArticleDOI
Exploring YSZ/ZrO2 - PuO2 systems: Candidates for inert matrix fuel
Chiranjit Nandi,Chiranjit Nandi,Vinita Grover,Vinita Grover,Koushik Bhandari,Shovit Bhattacharya,Sudhir Mishra,Joydipta Banerjee,Amrit Prakash,A. K. Tyagi,A. K. Tyagi +10 more
TL;DR: In this article, phase relations in yttria stabilized zirconia (YSZ) and ZrO2-PuO2 systems were investigated by employing PuO2 directly instead of surrogates.
References
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Journal ArticleDOI
A rapid and specific titrimetric method for the precise determination of uranium using iron(II) sulphate as reductant
W. Davies,W. Gray +1 more
TL;DR: In this paper, a procedure has been developed which enables uranium to be determined without chemical separation in solutions containing iron, plutonium, nitrate and many other foreign ions, which interfere in conventional redox methods.
Journal ArticleDOI
Derivative Polarographic Titrations
Journal ArticleDOI
The Quantitative Separation of Plutonium from Various Ions by Anion Exchange.
I.K. Kressin,G.R. Waterbury +1 more
TL;DR: In this paper, the anion exchange resin separation of plutonium was investigated as a possible technique for the rapid quantitative separation of the plutonium from various metal ions, and a slurry-column technique provided satisfactory separation of a plutonium from quite a large number of metal ions.
Journal ArticleDOI
Cerimetrie en milieu nitrique. application au dosage du fer, de l'uranium et du plutonium
J. Corpel,F. Regnaud +1 more
TL;DR: In this article, the methode decrite permet d'effectuer le dosage du fer, de luranium ou du plutonium en milieu nitrique par volumetric.
Journal ArticleDOI
Argentic oxide as an oxidimetric reagent determination of manganese, cerium and chromium
James J. Lingane,Donald G. Davis +1 more
TL;DR: Argentic oxide, AgO, is commercially available (Merck) in pure form, and it serves advantageously as a very powerful oxidimetric reagent in acid media as discussed by the authors.
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A rapid and specific titrimetric method for the precise determination of uranium using iron(II) sulphate as reductant
W. Davies,W. Gray +1 more