Journal ArticleDOI
Radiolytic decomposition of solid oxalic acid
O. Gal,P.J. Baugh,G.O. Phillips +2 more
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In this paper, it was shown that there is no significant difference in the radiolytic decomposition of the following forms of oxalic acids: dihydrate, anhydrous and freeze-dried.About:
This article is published in The International Journal of Applied Radiation and Isotopes.The article was published on 1971-06-01. It has received 2 citations till now. The article focuses on the topics: Oxalic acid & Anhydrous.read more
Citations
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Journal ArticleDOI
Gamma radiolysis of oxalic acid and selected metal oxalates
P.L. Dougherty,W.C. Gottschall +1 more
TL;DR: Solid samples of hydrated and anhydrous oxalic acid were irradiated with doses of 1 to 200 Mrad of gamma radiation and carbon dioxide and water were determined to be the major decomposition products of radiolysis.
Journal ArticleDOI
Gamma radiolysis of selected metal oxalates
P.L. Dougherty,W.C. Gottschall +1 more
TL;DR: In this paper, the amount of radiation protection by the inclusion of the bivalent transition metal ion is variable but significant, and is in part dependent upon the ability of the metal ion to undergo reduction.
References
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Journal ArticleDOI
The Radiolysis of Crystalline Oxalato Metal Complexes. The Effects of Coordinating Metal Ions on the Radiolysis of Oxalate
TL;DR: In this paper, the reaction of the ligand is also affected by the central metal ions and the coupled reduction of central metal ion with the oxidative decomposition of ligand to carbon dioxide occurs at relatively high G values.
Journal ArticleDOI
Energy transport in carbohydrates. Part II. Radiation decomposition of D-glucose
TL;DR: In this article, a direct isotope dilution analysis has been employed to measure the degradation of anhydrous α- and β-D-glucose and α-D-, D-, and D-, monohydrate monohydrate on γ-irradiation.
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Energy transport in carbohydrates. Part III. Chemical effects of γ-radiation on the cycloamyloses
G. O. Phillips,M. Young +1 more
TL;DR: On the other hand, on irradiation of cyclohepta-amylose in aqueous solution (8 × 10 −3M), there is a different distribution of products, and cleavage of the cyclic system is more akin to acid hydrolysis as mentioned in this paper.
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Radiolysis of crystalline oxalato complexes
TL;DR: Several crystalline metal oxalato complexes were irradiated with Co/sup 6/sup 0/ gamma rays and found to be very stable to gamma radiation, compared with those in metal ox alato complexes as discussed by the authors.
Journal ArticleDOI
The radiolysis of solid oxalic acid and ammonium oxalate induced by mixed pile and 60Co gamma radiation
TL;DR: In this paper, the radiolysis of anhydrous and oxalic acid dihydrate and ammonium oxalate in the solid state by mixed pile and 60 Co γ-radiation was studied at doses up to ca. 1000 megarads when about 50 per cent decomposition occurred.