Journal ArticleDOI
Studies in Macrolide Synthesis: A Stereocontrolled Synthesis of Oleandolide Employing Reagent- and Substrate-Controlled Aldol Reactions of (S)-1-(Benzyloxy)-2-methylpentan-3-one
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This article is published in Journal of the American Chemical Society.The article was published on 1994-12-01. It has received 132 citations till now. The article focuses on the topics: Substrate (chemistry) & Aldol reaction.read more
Citations
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Journal ArticleDOI
Macrolactonizations in the Total Synthesis of Natural Products
Journal ArticleDOI
Modern aldol methods for the total synthesis of polyketides.
Bernd Schetter,Rainer Mahrwald +1 more
TL;DR: This Review illustrates by means of selected syntheses of natural products the new variants of the aldol addition, which includes a Aldol additions with various metal enolates, as well as metal-complex-catalyzed, organocatalytic, and biocatalysis methods.
Journal ArticleDOI
Macrocyclization Reactions: The Importance of Conformational, Configurational, and Template-Induced Preorganization
TL;DR: This paper aims to demonstrate the efforts towards in-situ applicability of EMMARM, which aims to provide real-time information about concrete mechanical properties such as E-modulus and compressive strength.
Journal ArticleDOI
The SAMP-/RAMP-hydrazone methodology in asymmetric synthesis
Journal ArticleDOI
A practical synthesis of (+)-discodermolide and analogues: fragment union by complex aldol reactions.
TL;DR: In this paper, a practical stereocontrolled synthesis of (+)-discodermolide (1) has been completed in 10.3% overall yield (23 steps longest linear sequence).
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