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Synthesis and X‐Ray Crystal Structure of a Polymeric Iodobismuthate Anion.

The reaction between [CH2=C(C6H4-4-NO2)CH2NMe3]I and eight equivalents of BiI3 in thf (tetrahydrofuran) afforded, after work-up, dark red crystals of the compound [CH2=C(C6H4-4-NO2)CH2NMe3]n[{Bi2I7}n], the structure of which was established by X -ray crystallography and shown to contain a polymeric iodobismuthate anion. An analogous reaction between [CH3(CH2)2COS(CH2)2N(CH3)3]I and eight equivalents of BiI3 afforded orange crystals of the compound [CH3(CH2)2COS(CH2)2N(CH3)3]4[Bi4I16] which was shown by X -ray crystallography to contain the tetranuclear [Bi4I16]4- anion.

Synthesis and X‐Ray Crystal Structure of a Polymeric Iodobismuthate Anion.

References

Synthesis and x-ray crystal structure of a polymeric iodobismuthate anion

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