Journal ArticleDOI
Synthesis and X-ray structural study of 1-adamantylmethyl 2-cyanoacrylate and 1,10-decanediol bis-2-cyanoacrylate
Victor N. Khrustalev,Oleg V. Shishkin,Sergey Lindeman,Yu. T. Struchkov,M. A. Galkina,Yu. G. Gololobov +5 more
TLDR
I-Adamantylmethyl 2-cyanoacryloyl chloride with 1-adamantylmethanol was synthesized by transesterification of methyl 2-cyanacrylate with 1,10-decanediol as discussed by the authors.Abstract:
I-Adamantylmethyl 2-cyanoacrylate (1) was prepared by the reaction of 2-cyanoacryloyl chloride with 1-adamantylmethanol . 1,10-Decanediol bis-2-cyanoacrylate (2) was synthesized by transesterification of methyl 2-cyanoacrylate with 1,10-decanediol. Esters1 and2 were studied by X-ray structural analysis.read more
Citations
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Patent
Method of preparing electron deficient olefins in polar solvents
TL;DR: In this paper, a process for producing electron deficient olefins, such as 2-cyanoacrylates, in a polar solvent such as an ionic liquid was described.
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Transferable curable non-liquid film on a release substrate
TL;DR: In this paper, transferable curable non-liquid film on a release substrate, comprising at least one curable component which is an electron deficient olefin component, process for making same, bonding processes utilising same, assemblies comprising substrates bonded together using same and the cure product of said films are also described.
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Electron deficient olefins
TL;DR: In this paper, the electron deficient olefins, such as 2-cyanoacrylates and methylidene malonates, were prepared using an imine or an iminium salt.
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Method of preparing electron deficient olefins
TL;DR: In this paper, a process for producing electron deficient olefins, such as 2-cyanoacrylates, using an iminium salt, and if desired contacting the reaction byproduct with alkali to generate an amine and separating that amine therefrom.
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Activated methylene reagents and curable compositions prepared therefrom
TL;DR: In this article, the authors introduce active methylene reagents, a class of compounds with ester linkage(s) capped with either electron deficient olefinic linkage or reactive functional groups.
References
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Journal ArticleDOI
Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds
TL;DR: The average lengths of bonds involving the elements H, B, C, N, O, F, Si, P, S, Cl, As, Se, Br, Te, and l in organic compounds are reported in this article.
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Unequivocal synthesis of bis(2‐cyanoacrylate) monomers. I. Via anthracene adducts
Journal ArticleDOI
Preparation, structure and asymmetric Diels-Alder reactions of 10-arylsulfonylisobornyl acrylates
TL;DR: The crystalline chiral auxiliaries 4 and 5 were readily prepared from camphorsulfonic acid and their acrylates underwent the diels-alder reactions 6 → 7 with modest asymmetric induction consistent with an X-ray study of 6a.
Journal ArticleDOI
2-Cyanoacrylates as reagents in heteroatomic synthesis (a review)
TL;DR: Several types of addition reactions to the CC bond of alkyl 2-cyanoacrylates, CH2C(CN)COOR (1), are considered in this article.