Journal ArticleDOI
Synthesis of triblock copolymers (polyA-polybutadiene-polyA) and applications as additives in composite propellants
V. Vasudevan,G. Sundararajan +1 more
TLDR
In this article, the authors used triblock copolymers obtained from HTPB as additive to a solid propellant mixture based on HTPB with ammonium perchlorate (oxidiser), dioctyl adipate (plasticiser), and toluene diisocyanate (curing agent).Abstract:
Hydoxyl-terminated polybutadiene (HTPB), an important polymeric fuel binder for composite propellants, has been utilised to anchor tungsten hexachloride, a well-known metathesis catalyst. This anchored catalyst polymerises various monomers like phenylacetylene (PA) and norbornene (NBE) to give triblock copolymers via metathesis polymerisation. The triblock copolymers thus obtained are of the type polyA-block-polybutadiene-block-polyA and have been characterised by spectroscopic, thermal and gel permeation chromatographic techniques. As block copolymers have the characteristics of the individual polymers, they can be used as substitutes or additives in analogous polymeric formulations to improve the matrix properties. These triblock copolymers obtained from HTPB were employed as additives to a solid propellant mixture based on HTPB with ammonium perchlorate (oxidiser), dioctyl adipate (plasticiser) and toluene diisocyanate (curing agent). Burning rate studies of these propellant mixtures were conducted under various pressures to evaluate the individual ballistic nature. It was found that NBE-based additive imparts higher burning rate than the HTPB-based propellant. The effect of copper chromite as a burning rate modifier in this new formulation was also evaluated. The mechanical properties of the propellants were measured and compared to show the effect of triblock in the binder network. This paper mainly focuses on the synthesis and characterisation of the above triblock copolymers and burning rate studies of the propellants based on these polymers.read more
Citations
More filters
Journal ArticleDOI
Synthesis of azido polymers as potential energetic propellant binders
TL;DR: In this article, the authors discuss the various synthetic routes for preparation of high energetic polymeric binders, including glycidyl azide polymers (GAP)s, GAP co-polymers, oxetane polymers and oxirane polyesters, N, N′-bonded epoxy binders.
Journal ArticleDOI
Synthesis and characterization of HTPB-GAP cross-linked co-polymers
Y. Murali Mohan,K. Mohana Raju +1 more
TL;DR: In this article, a cross-linked co-polymer containing GAP and hydroxyl-terminated poly(butadiene) segments has been obtained by chemical reactions.
Journal ArticleDOI
Hydroxyl Terminated Polybutadiene: Chemical Modification and Application of these Modifiers in Propellants and Explosives
TL;DR: In this paper, the chemical modification of hydroxyl terminated polybutadiene (HTPB) for improving certain properties of propellants has been summarized in detail in the literature.
Journal ArticleDOI
Synthesis and Characterization of Low Molecular Weight Azido Polymers as High Energetic Plasticizers
Y. Murali Mohan,K. Mohana Raju +1 more
TL;DR: In this article, the authors described a convenient process for the preparation of low molecular weight hydroxyl-terminated glycidyl azide polymers using diols as initiators in the presence of sodium azide.
Journal ArticleDOI
Preparation of CuO Modified SBA-15 and Applications as Catalyst in AP/HTPB Solid State Propellants
TL;DR: In this article, a mesoporous silica SBA-15 composite was used as a catalyst to increase the burning rate of a composite solid propellant, and the dispersibility of CuO was enhanced significantly.
References
More filters
Journal ArticleDOI
Living Polymerization Methods
TL;DR: Living polymerization techniques can be used to achieve a high degree of control over polymer chain architecture, which results in polymers with widely diverse physical properties, even though they are made from readily available low-cost monomers.
Journal ArticleDOI
Polymerization of acetylenic derivatives. XXX. Isomers of polyphenylacetylene
TL;DR: In this paper, a method was developed for determination of cis content of cis-transoidal and cis-cisoidal polyphenylacetylenes (PPA) by using Ziegler-Natta catalysts.
Book
Solid rocket propulsion technology
TL;DR: The main families and use of solid propellants, A. Davenas as mentioned in this paper, B. Gondouin, B. Zeller, and H. Austruy.
Journal ArticleDOI
Polymerization of Phenylacetylenes. I. Polymerization of Phenylacetylene Catalyzed by WCI6and MoCI5
Journal ArticleDOI
Role of Binders in Solid Propellant Combustion
TL;DR: In this article, the effects of inert binder properties on composite solid propellant burning rate were investigated and defined for many binders of practical interest over a wide range of heating rates and pressures, in several environmental gases, with and without 10 percent ammonium perchlorate (AP) contained in the sample, and in some cases with catalysts.