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Synthesis, structure and photochromic properties of indoline spiropyrans with electron-withdrawing substituents

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TLDR
Indoline spiropyrans containing conjugated cationic vinyl-3H-indolium fragment and their analogues with formyl substituent in the 2H-chromene moiety were synthesized by a simple one-pot method.
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This article is published in Journal of Molecular Structure.The article was published on 2021-04-05. It has received 16 citations till now. The article focuses on the topics: Spiropyran & Moiety.

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Spiropyran-based Advanced Photoswitchable Materials: A Fascinating Pathway to the Future Stimuli-responsive Devices

TL;DR: In this paper , the most recent observations and efforts in the progress of photoswitchable spiropyran-based materials and their applications as sensors for heavy metal cations, anions, pH, acid and base vapors, wettability and humidity.
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Novel polychromogenic fluorine-substituted spiropyrans demonstrating either uni- or bidirectional photochromism as multipurpose molecular switches

TL;DR: In this article , photochromic spiropyrans (SPPs) with fluorine substituents and cationic fragments or formyl groups at positions 6′ and 8′ of the 2H-chromene moiety were synthesized using a simple one-pot method.
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Structure and Properties of 1,3,3-Trimethyl-6′-chlorospiro[indoline-2,2′-2H-chromene]

TL;DR: In this article, a single crystal X-ray diffraction analysis of spiropyran was performed using the CrystalExplorer17 software package to investigate the features of the crystal structure and intermolecular interactions.
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Construction of pillar[5]arene-based photochromic supramolecular polymeric system with tunable thermal bleaching rate

TL;DR: In this paper, a photochromic supramolecular system with pillar[5]arene subunit and naphthopyran moiety in the chemical structural backbone is presented.
References
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Journal ArticleDOI

Spiropyran-based dynamic materials

TL;DR: This review discusses the synthesis, switching conditions, and use of dynamic materials in which spiropyran has been attached to the surfaces of polymers, biomacromolecules, inorganic nanoparticles, as well as solid surfaces.
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Organic photochromism (IUPAC Technical Report)

TL;DR: In this article, a general introduction to organic photo-chromism is given together with that of words with the ending "chromism", such as thermo-, electro-, piezo-, and tri-bochromism.
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Molecular switches as photocontrollable “smart” receptors

TL;DR: This critical review focuses on the development of photochromic compounds as sensors for cations, anions, and biologically important molecules and a summary of photoswitchable receptors emerged to date and classified according to the photo chromic structure they are based on.
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The evolution of spiropyran: fundamentals and progress of an extraordinarily versatile photochrome.

TL;DR: An overview of their rich history is provided and the contemporary relevance of the spiropyrans is highlighted.
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