Journal ArticleDOI
The free-radical reaction of the methyl ester and nitrile of 3-methoxypropionic acid with alk-1-enes
TLDR
The free-radical addition of the methyl ester and nitrile of 3-methoxypropionic add to alkenes, initiated with ditert-butyl peroxide, leads to the formation of 1:1 adducts which consist of methyl esters or nitriles of 2-alkyl-3methoxide, 3-alky-3 methoxy-, 3-alkyl-3-methyltimoxy-, and 3 -alkoxy substituted propionic acids.Abstract:
1.
The free-radical addition of the methyl ester and nitrile of 3-methoxypropionic add to alkenes, initiated with ditert-butyl peroxide, leads to the formation of 1:1 adducts which consist of the methyl esters or nitriles of 2-alkyl-3-methoxy-, 3-alkyl-3-methoxy-, and 3-alkoxy substituted propionic acids.
2.
The reaction is accompanied by the formation of a small quantity of by-products produced by the partialβ-dissociation of the CH2OCH2CH2COOCH3 and CH3OCHCH2COOCH3 radicals.read more
References
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Journal ArticleDOI
β-Alkoxypropionates. Addition of Alcohols to the Olefinic Linkage of Alkyl Acrylates
Journal ArticleDOI
Communications- The Free Radical Chemistry of Cyclic Ethers: A Novel Free Radical Rearrangement
T Wallace,R Gritter +1 more
Journal ArticleDOI
Synthetic aspects of free radical addition reactions. Part V. Alkylation of compounds containing activated methylene and methine groups
TL;DR: In this paper, the free-radical induced addition reactions of oct-1-ene and the following compounds containing activated methylene or methine groups have been investigated: diethyl butylmalonate, di-isopropyl malonate (DIMM), diethryl acetoacetate, diethrynyl cyanomalonate(CYM), triethoxy carbonylmethane, 1,1,2-triethoxycarbonylethane, ethyl diacetylacetate (EDE), ethyl