Transference of Water to the Nitrobenzene Phase for the Extraction of Tris(1,10-phenanthroline)iron (II) and Tris(2,2′-bipyridine)iron(II) Chelate Salts
TLDR
In this paper, the amount of water transferred to the nitrobenzene phase was determined for the extraction of ion pairs of tris(1,10-phenanthroline)iron(II) and tris (2,2′-bipyridine) iron(II), with halide and pseudohalide anions.Abstract:
The amount of water transferred to the nitrobenzene phase was determined for the extraction of ion pairs of tris(1,10-phenanthroline)iron(II) and tris(2,2′-bipyridine) iron(II) with halide and pseudohalide anions. For both chelate systems the smaller the anion, the greater the amount of water transported, very similar results being obtained for a common anion. The results were discussed in relation to water of crystallization, extractability and temperature effect.read more
Citations
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Proton NMR Study on Selective Hydration of Anions in Nitrobenzene
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References
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Journal ArticleDOI
Heat of Solution of Tris(1, 10-Phenanthroltne)Iron(II) Salts in Water and in Nitrobenzene
Y. Yamamoto,T. Tarumoto +1 more
TL;DR: In this article, the solvent extraction of ion pairs of tris(1, 10-phenanthroline)iron(II) chelate cations with halide, thiocyanate and perchlorate anions from wate...
Journal ArticleDOI
Water Adduct Formation in Extracted Chelates
TL;DR: Water adducts of 1,10-phenanthroline, 4,7-diphenyl-1,10phenanthyl, 2,9-dimethyl-1.10-pthynthine, tris(4,7diphensyl)-1, 10pthnthine) Fe(II) perchlorate and bis(2,9dimethyl)-1.5-dimethane were found to have 5.1 ± 0.9, 0 ± 1.3, 6.6, 5.
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