Showing papers on "Cadmium acetate published in 1969"
TL;DR: In this paper, an increase in mortality was found in direct relation to the amount of cadmium in the diet of mice, and liver and heart tissues exhibited increased malic dehydrogenase and glucose-6-phosphate dehydrogenases activities when 412 and 4120 ppm of Cadmium was fed.
24 citations
TL;DR: Cadmiumacetate reacts in anhydrous acetic acid with acetyl halides, ammonium halides or by means of the so-called "halogen-acetone method" to form cadmium halide acetates Cd(Hal)x(CH3COO)2−x, (Hal Cl−, Br−, J−) as discussed by the authors.
Abstract: Cadmiumacetat reagiert in wasserfreier Essigsaure mit Acetylhalogeniden, Ammoniumhalogeniden oder mittels der „Halogen-Aceton-Methode” zu Cadmiumhalogenidacetaten Cd(Hal)x(CH3Coo)2−x, (Hal Cl−, Br−, J−).
Cadmiumchloridacetat wird bei 320–330°C zu Cadmiumoxidchlorid zersetzt, wahrend Cadmiumbromidacetat und Cadmiumjodidacetat in der Hitze ein Gemenge von Cadmiumoxid und Cadmiumhalogenid liefern.
Die Cadmiumhalogenidacetate konnen durch Reaktion mit anderen Halogeniden dazu benutzt werden, gemischte Cadmiumhalogenide zu bilden, z. B. CdBr1,2Cl0,8.
Cadmium acetate reacts in anhydrous acetic acid with acetyl halides, ammonium halides or by means of the so-called “halogen-acetone method” to form cadmium halide acetates Cd(Hal)x(CH3COO)2−x, (Hal Cl−, Br−, J−).
Cadmium chloride acetate is decomposed to cadmium oxide chloride at 320–330°C, whereas cadmium bromide acetate and cadmium jodide acetate give a mixture of cadmium oxide and cadmium halide on heating.
The cadmium halide acetates can be used to form mixed cadmium halides by reaction with other halides, e. g. CdBr1.2Cl0.8.
1 citations
TL;DR: In this paper, the thermodynamic data of the reaction, Cd(c) + Hg2Ac2(c)=2Hg(l)+Cd++(aq)+2Ac−(aq) at 25°C were estimated as ΔFf°=−42,139.
Abstract: E. M. F. of the Cell, Cd-Hg (2-phase)/CdAc2(m), Hg2Ac2(s)/Hg was measured at 20°, 25°, 30° and 40°C. The standard e. m. f. of the cell, Cd/CdAc3(m), Hg2Ac2(c)/Hg was evaluated as E°=1.1500−11.09×10−4T+1.06×10−8T2 The thermodynamic data of the reaction, Cd(c) + Hg2Ac2(c)=2Hg(l)+Cd++(aq)+2Ac−(aq) at 25°C were estimated as ΔF°=−42,139, ΔH°=−48,698 cal mole−1 and ΔS°=−22.0 cal deg−1 mole−1 at 25°C. The thermodynamic data for the formation of Hg2Ac2(s) were evaluated as ΔFf°=−202.3, ΔHf°=−154.5 Kcal mole−1 and S°=72.9 cal deg−1 mole−1. From measurements of the heats of solution of CdAc2·2H2O in aqueous solution, the relative partial molal enthalpies of cadmium acetate in aqueous solution were estimated.