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Showing papers on "Dichlorophenylphosphine published in 1984"



Journal ArticleDOI
TL;DR: In this paper, a one-pot synthesis of cyclic tertiary phosphines from dichlorophenylphosphine is described, where the first stage consists of condensation of one equivalent of an organocadmium and substitution of the second by another organometallic compound.

11 citations


Journal ArticleDOI
TL;DR: The formation of alkyl chlorides in the reactions of alcohols with phosphorus trichloride, dichlorophenylphosphine, or chlorodiphenyl phosphine involves the dealkylation of an intermediate phosphorus(III) ester by hydrogen chloride as mentioned in this paper.
Abstract: The formation of alkyl chlorides in the reactions of alcohols with phosphorus trichloride, dichlorophenylphosphine, or chlorodiphenylphosphine involves the dealkylation of an intermediate phosphorus(III) ester by hydrogen chloride (Scheme 1).1–3 An analogous dealkylation occurs in the reactions of hydrogen chloride with triphenyl phosphite-alcohol mixtures (Scheme 2).4