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Showing papers on "Glycal published in 1985"





Journal ArticleDOI
TL;DR: The monoacetates of L-fucal underwent O-3----O-4 migration of the acetyl group, and selective acylation of this glycal could not be achieved.

27 citations



Journal ArticleDOI
TL;DR: In this paper, a RuO4-catalyzed oxidative cleavage of 6-deoxyglucal diacetate (5d) derived from D-glucalin triacetate was performed, followed by alkaline hydrolysis and acidic work up.
Abstract: 5-Deoxy-D-arabinono-1,4-lactone (2) was synthesized by a RuO4-catalyzed oxidative cleavage of 6-deoxyglucal diacetate (5d), derived from D-glucal triacetate (3), followed by alkaline hydrolysis and acidic work-up.

17 citations


Journal ArticleDOI
TL;DR: Treatment of a solution of the 2-O-(N,N-dimethylsulfamoyl) derivative 3 of the levoglucosenone-derived carbocycle 1 in liquid ammonia gave 73% of the glycal derivative 4 instead of the expected 2-deoxy derivative (2) of 1.

4 citations